Triphenylbismuth

HCID 11774CAS 603-33-8
Substructure searchFind similar structures

Basic information

Standard SMILES
c1cc[c]([Bi]([c]2ccccc2)[c]2ccccc2)cc1
InChIKey
ZHXAZZQXWJJBHA-UHFFFAOYSA-N
Molecular formula
C18H15Bi
Average molar mass
440.3 g/mol
Monoisotopic mass
440.09777418

Overview

structure given in first source

Names & identifiers

Preferred name
Triphenylbismuth
IUPAC
triphenylbismuthane
English name
Triphenylbismuth
Molecular formula
C18H15Bi
Molecular weight
440.29

Names & synonyms

Triphenylbismuth603-33-8TriphenylbismuthineTriphenyl bismuthBISMUTHINE, TRIPHENYL-AerotexTrifenylbismutinDTXSID6042498Triphenyl bismuthineNSC-465R18732F41WDTXCID4022498
Show more names
TPB(C6H5)3Bitriphenyl-bismuthinTriphenylbismuth,99%Triphenylbismuth,98%
Ph3BiRefChem:191900210-033-4triphenylbismuthaneBismuth triphenylBismuth, triphenyl-MFCD00014064Caswell No. 896

Database identifiers

CAS
603-33-8
PubChem CID
11774
DTXSID
DTXSID6042498
UNII
R18732F41W
EC Number
210-033-4
Nikkaji
J42.067K

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
0
Rotatable bonds
3
Heavy atoms
19

Experimental & physicochemical properties

Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure0.000034 [mmHg]
Physical Description · 2 items

CBI

Solid; [Merck Index] White to off-white powder; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
78 · 78-80 °C
Boiling point
310 °C · 310°C
Density
1 · 1,585 g/cm3
refractive index
1.704 · 1.7040
Flash point
242 °C/14mm · 242°C/14mm
storage temp.
Inert atmosphere,Room Temperature

Safety & regulation

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.

Warning

H302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Hazard Traits - Bioaccumulation; Environmental Persistence

Bismuthine, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Bismuthine, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Bismuthine, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Triphenylantimony.
Hazard Classes and CategoriesAcute Tox. 4 (95.7%)

Safety data

wgk
3
tsca
TSCA listed
rtecs
EB2980000
hs_code
29319090
risk_code
20/21/22
Signal word
Warning

Chemistry & industry

Uses & manufacturing

UsesUsed as a radiopacifying agent in dental resins and medical devices, polymerization catalyst, and in organic synthesis; [Merck Index]
U.S. Production2023: <50,000 lb
Industry UsesOther
General Manufacturing Information · 2 items

All Other Chemical Product and Preparation Manufacturing

Bismuthine, triphenyl-: ACTIVE

Applications · 1 item

UsesTriphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

Preparation methods

PreparationTriphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.

Upstream & downstream products

Suppliers50 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海策嵘生物科技有限公司[email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]

Related reactions

7 records
New reaction record

Linked notes

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