CAS 932-32-1 Benzenamine, 2-chloro-N-methyl- (HCID 136736)

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Basic information

CAS: 932-32-1
Standard SMILES: CNc1ccccc1Cl
InChIKey: WGNNILPYHCKCFF-UHFFFAOYSA-N
Molecular formula: C7H8ClN
Average molar mass: 141.6 g/mol
Monoisotopic mass: 141.03452694

Names & identifiers

Preferred name: Benzenamine, 2-chloro-N-methyl-
IUPAC: 2-chloro-N-methylaniline
English name: 2-CHLORO-N-METHYLANILINE
Molecular formula: C7H8ClN
Molecular weight: 141.6

Names & synonyms

2-Chloro-N-methylaniline932-32-1Benzenamine, 2-chloro-N-methyl-DTXSID50239323RefChem:561688DTXCID70161814624-653-1N-Methyl-2-chloroanilineMFCD000451702-Chloro-N-methylbenzenamine2-chloro-N-methyl-aniline2-chlor-n-methylaniline

Show more names

N-Methyl-o-chloroanilineo-Chloro-N-methylanilineN1-METHYL-2-CHLOROANILINE2-Chloro-N-methylbenzylamineo-Chloro-N-methylbenzenamine2-(Methylamino)chlorobenzene2-Chloro-N-methylaniline ,97%

2-chloro-N-methyl anilineSCHEMBL100946(2-chloro-phenyl)-methyl-amineSY048562C3121CS-0095956EN300-12541052-chloranyl-N-methyl-aniline

Database identifiers

CAS: 932-32-1
PubChem CID: 136736
DTXSID: DTXSID50239323
EC Number: 624-653-1
Nikkaji: J364.607F

Properties

Computed structural properties

XLogP: 2.5
Topological polar surface area: 12 Å²
Hydrogen bond donors: 1
Hydrogen bond acceptors: 1
Rotatable bonds: 1
Heavy atoms: 9
Formal charge: 0
Complexity: 85

Experimental & physicochemical properties

SpringerMaterials PropertiesOptical coefficient

Physicochemical properties

Boiling point: 218 °C · 218 °C (lit.)
Density: 1.15 g/mL · 1.15 g/mL at 25 °C (lit.)
refractive index: 20 · n20/D 1.579(lit.)
Flash point: 198 °F · 198 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Not miscible or difficult to mix.
pka: 3.17 · 3.17±0.10(Predicted)
form: clear liquid
color: Colorless to Red to Green
BRN: 2802444 · 2802444
InChI: 1S/C7H8ClN/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,1H3
InChIKey: WGNNILPYHCKCFF-UHFFFAOYSA-N
SMILES

Safety & regulation

GHS classification

GHS Classification · 4 items

Warning

H302 (12.8%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesAcute Tox. 4 (12.8%)

Safety data

PPE: Eyeshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 3
ridadr: 2810
hs_code: 29214200
risk_code: 36/37/38
Signal word: Warning
Symbol(GHS): GHS06,GHS08,GHS07
hazard_code: Xi
safety_code: 26-36
hazard_class: 6.1
Storage Class: 10 - Combustible liquids
packing_group: III
target organs: Respiratory system
Hazard statements: H315-H319-H335-H227-H302-H312-H331-H373
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P210e-P260-P280-P405-P501a-P261-P305+P351+P338

Chemistry & industry

Applications

Uses2-Chloro-N-methylaniline is used to produce 1-methyl-2-thioacetylpyrrole in the presence of reagent Lawesson's reagent and solvent tetrahydrofuran.

General Description2-Chloro-N-methylaniline (2-Cl-N-MA), also known as N-methyl-2-chloroaniline, is a secondary amine. The iridium-catalyzed borylation of 2-Cl-N-MA affords the correponding ortho-borylated derivative.