CAS 5933-32-4 4-Bromobenzohydrazide (HCID 22219)

Names & identifiers

Preferred name: 4-Bromobenzohydrazide
IUPAC: 4-bromobenzohydrazide
English name: 4-Bromobenzhydrazide
Molecular formula: C7H7BrN2O
Molecular weight: 215.05

Names & synonyms

4-BromobenzohydrazideUYIMBYKIIMYFPS-UHFFFAOYSA-RefChem:520466227-681-9InChI=1/C7H7BrN2O/c8-6-3-1-5(2-4-6)7(11)10-9/h1-4H,9H2,(H,10,11)5933-32-44-Bromobenzhydrazide4-Bromobenzoic hydrazidep-Bromobenzhydrazide4-Bromobenzoic acid hydrazidep-Bromobenzoic acid hydrazideBenzoic acid, 4-bromo-, hydrazide

Show more names

P-BROMOBENZOYLHYDRAZINE4-Bromobenzohydrazide >4-Bromobenzhydrazide, 98+%p-bromo-benzoicacihydrazide

4-BromobenzoylhydrazineMFCD00007602BENZOIC ACID, p-BROMO-, HYDRAZIDE4-bromobenzenecarbohydrazidep-BromobenzohydrazideNSC60114NSC-60114(p-Bromobenzoyl)hydrazine

Database identifiers

CAS: 5933-32-4
PubChem CID: 22219
DTXSID: DTXSID80208062
ChEMBL: CHEMBL124433
UNII: ZB65YY5L9G
EC Number: 227-681-9
Nikkaji: J41.209K

Properties

Computed structural properties

XLogP: 1.3
Topological polar surface area: 55.1 Å²
Hydrogen bond donors: 2
Hydrogen bond acceptors: 2
Rotatable bonds: 1
Heavy atoms: 11
Formal charge: 0
Complexity: 143

Physicochemical properties

Melting point: 167 · 167-169°C
Density: 1.615 · 1.615±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Powder
pka: 12.09 · 12.09±0.10(Predicted)
color: Light beige
Water Solubility: Soluble in hot methanol (almost transparency). Slightly soluble in water.
BRN: 777006 · 777006
InChI: InChI=1S/C7H7BrN2O/c8-6-3-1-5(2-4-6)7(11)10-9/h1-4H,9H2,(H,10,11)
InChIKey: UYIMBYKIIMYFPS-UHFFFAOYSA-N
SMILES: C(NN)(=O)C1=CC=C(Br)C=C1
CAS DataBase Reference: 5933 · 5933-32-4(CAS DataBase Reference)
EWG's Food Scores: 1 · 1
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 7 · GHS07
Signal word: Warning
Hazard statements: 315 · H315-H319-H335
Precautionary statements: 261 · P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: 95 · dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes: Xi
Risk Statements: 36 · 36/37/38
Safety Statements: 26 · 26-36/37/39-37/39
WGK Germany: 3 · 3
RTECS: 4449250 · DG4449250
HS Code: 29280000 · 29280000
Storage Class: 11 · 11 - Combustible Solids
Hazard Classifications: 2 Skin · Eye Irrit. 2Skin Irrit. 2STOT SE 3

Safety & regulation

GHS classification

GHS Classification · 5 items

Warning

H315 (97.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (97.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (95.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Hazard Classes and CategoriesSkin Irrit. 2 (97.8%)；Eye Irrit. 2 (97.8%)；STOT SE 3 (95.7%)

Safety data

PPE: dust mask type N95 (US), Eyeshields, Gloves
wgk: 3
rtecs: DG4449250
hs_code: 29280000
risk_code: 36/37/38
Signal word: Warning
Symbol(GHS): GHS07
hazard_code: Xi
safety_code: 26-36/37/39-37/39
Storage Class: 11 - Combustible Solids
target organs: Respiratory system
Hazard statements: H315-H319-H335
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338

Chemistry & industry

Applications · 1 item

Uses4-Bromobenzoic hydrazide has been used in the preparation of {2-[1-oxo-3-(4-bromophenyl)-2-propenyl]hydrazide}-4-bromobenzoic acid, {2,2-[1,4-phenylenebis(1-oxo-2-propene-3,1-diyl)]dihydrazide}-p-bromobenzoic acid and substituted period[1,2-a]pyrimidine-2,4(3H)-diones (PPMDO).