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Iodic acid

HCID 24345
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
25659-31-8
Standard SMILES
[O-][I+2]([O-])O
InChIKey
ICIWUVCWSCSTAQ-UHFFFAOYSA-N
Molecular formula
HIO3
Average molar mass
175.911 g/mol
Monoisotopic mass
175.89704

Overview

Iodic acid is an iodine oxoacid. It has a role as an astringent. It is a conjugate acid of an iodate.

Names & identifiers

Preferred name
Iodic acid
IUPAC
iodic acid
English name
LEAD IODATE
Molecular formula
H3IO3Pb
Molecular weight
385.13

Names & synonyms

Iodic acid7782-68-5Monoiodic acidIodic acid (HIO3)6U8J18JSBMCHEBI:24857DTXSID2064812RefChem:923486DTXCID9048013231-962-1HIO3Iodsaeure
Show more names
LEAD IODATELead(Ⅱ)iodatelead diiodateLEAD(II) IODATElead(2+),diiodateLEAD(II) IODATE, 99.99%Bisiodic acid lead(II) saltiodicacid(hio3),lead(2++)saltLEAD IODATE ISO 9001:2015 REACHIodicacid (HIO3), lead(2+) salt (2:1)
trioxoiodic acidtrioxidoiodine(.)hydrogen trioxoiodatehydroxidodioxidoiodineHOIO2MFCD00011348hydroxy-lambda(5)-iodanedione[IO2(OH)]

Database identifiers

CAS
25659-31-8、7782-68-5
PubChem CID
24345
DTXSID
DTXSID2064812
ChEMBL
CHEMBL1161636
ChEBI
CHEBI:24857
UNII
6U8J18JSBM
EC Number
231-962-1
Nikkaji
J43.589I

Properties

Computed structural properties

XLogP
-0.3
Topological polar surface area
54.4 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
4
Formal charge
0
Complexity
46.2

Experimental & physicochemical properties

Chemical ClassesToxic Gases & Vapors -> Acids, Inorganic
SpringerMaterials Propertiesdielectric constant
Density4.629 @25 °C
Physical Description · 2 items

Dry Powder

Colorless solid; [Hawley] Colorless or light yellow powder; [MSDSonline] Forms rhombohedral crystals--decompose at 110 deg C; [Ullmann]

Physicochemical properties

Melting point
300 °C · 300 °C (dec.)(lit.)
Density
6.5 g/mL · 6.5 g/mL at 25 °C(lit.)
form
white orthorhombic crystals
color
white orthorhombic crystals, crystalline
Water Solubility
2 O: · g/L solution H2O: 0.0254 (25°C) [KRU93]
Solubility Product Constant (Ksp)
12.43 · pKsp: 12.43

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 6 items

Danger

H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

Hazard information

Regulatory Information · 4 items

Chemical: Iodic acid (HIO3)

Iodic acid (HIO3) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Iodic acid (HIO3) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Iodic acid (EC: 231-962-1)

Iodic acid: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Iodic acid and selected salts: Human health tier II assessment
Hazards Summary · 1 item

Reacts vigorously with organic matter; Oxidizes iodide to iodine, sulfite to sulfate, and hydrogen sulfide to sulfur; [Ullmann] Corrosive to skin and eyes; [eChemPortal: ERMA] May cause fire on contact with combustible materials; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline]

Hazard Classes and Categories · 2 items

Ox. Sol. 2 (100%)

Acute toxicity (ingestion) - category 4

Chemistry & industry

Uses & manufacturing

Uses · 2 items

Used as an astringent and disinfectant; [Merck Index] Used in analytical chemistry and in medicine (as 1-3% solution); [Hawley]

Using Disinfectants or Biocides [Category: Clean]

U.S. Production2023: 327,135 lb
Industry UsesFlavoring and nutrient
General Manufacturing Information · 2 items

Food, beverage, and tobacco product manufacturing

Iodic acid (HIO3): ACTIVE

Applications

UsesLEAD IODATE is used in for the preparation of fireworks.

Related reactions

81 records
New reaction record
HRID 86663 reaction equation
HRID 86663As reactantTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 110592 reaction equation
HRID 110592As reactantTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 145987 reaction equation
HRID 145987As reactantTraining data from https://doi.org/10.1039/C8SC04228D (9/10)
HRID 189659 reaction equation
HRID 189659As reactantTraining data from https://doi.org/10.1039/C8SC04228D (6/10)
HRID 256609 reaction equation
HRID 256609As reactantuspto-grants-1993_11
HRID 336073 reaction equation
HRID 336073As reactantuspto-grants-2014_11
HRID 342347 reaction equation
HRID 342347As reactantuspto-grants-1999_01
HRID 342352 reaction equation
HRID 342352As reactantuspto-grants-1999_01
Page 1 of 11

Compound notes

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REACH Annex XVII Substances List
Lead diiodate (25659-31-8)
EPA Substance Registry System
Lead(II) iodate (25659-31-8)
Symbol(GHS)
3 · GHS03,GHS07,GHS08,GHS09
Signal word
Danger
Hazard statements
272 · H272-H302-H332-H360-H373-H410
Precautionary statements
264 · P264-P270-P261-P271-P201-P202-P280-P260-P273-P301+P312-P330-P304+P340-P312-P308+P313-P314-P391-P405-P501
Hazard Codes
O,T,N
Risk Statements
61 · 61-8-20/22-33-50/53-62
Safety Statements
53 · 53-45-60-61
RIDADR
3087 · UN 3087 5.1/PG 3
WGK Germany
3 · 3
TSCA
TSCA listed

Safety & protection

Protective Action Criteria (PAC) · 3 items

1.5 [ppm]

17 [ppm]

100 [ppm]

Toxicology

Adverse EffectsDermatotoxin - Skin burns.

Safety data

wgk
3
tsca
TSCA listed
ridadr
UN 3087 5.1/PG 3
risk_code
61-8-20/22-33-50/53-62
Signal word
Danger
Symbol(GHS)
GHS03,GHS07,GHS08,GHS09
hazard_code
O,T,N
safety_code
53-45-60-61
Hazard statements
H272-H302-H332-H360-H373-H410
Precautionary statements
P264-P270-P261-P271-P201-P202-P280-P260-P273-P301+P312-P330-P304+P340-P312-P308+P313-P314-P391-P405-P501