Bromic acid

HCID 24445

Basic information

CAS
7789-31-3
Standard SMILES
[O-][Br+2]([O-])O
InChIKey
YTFCQDDTLVUOCN-UHFFFAOYSA-N
Molecular formula
BrHO3
Average molar mass
128.91 g/mol
Monoisotopic mass
127.91090599

Overview

Bromic acid is a bromine oxoacid. It is a conjugate acid of a bromate.

Names & identifiers

Preferred name
Bromic acid
IUPAC
bromic acid
English name
Bromic acid
Molecular formula
BrHO3
Molecular weight
128.91

Names & synonyms

Bromic acid7789-31-3908X3OZ87JDTXSID7064861CHEBI:49382HBrO3BromsaeurehydroxidodioxidobromineRefChem:121511(BrO2(OH))DTXCID9048065232-158-3
Show more names
Bromhydric acid
Bromsaureacide bromiqueacido bromicoacidum bromicumUNII-908X3OZ87JEINECS 232-158-3BROMIC ACID [MI]BROMIC ACID (HBRO3)

Database identifiers

CAS
7789-31-3
PubChem CID
24445
DTXSID
DTXSID7064861
ChEMBL
CHEMBL1161635
ChEBI
CHEBI:49382
UNII
908X3OZ87J
EC Number
232-158-3
Nikkaji
J95.891C

Properties

Computed structural properties

XLogP
-0.1
Topological polar surface area
54.4 Ų
Hydrogen bond donors
1
Hydrogen bond acceptors
3
Rotatable bonds
0
Heavy atoms
4

Experimental & physicochemical properties

Chemical ClassesToxic Gases & Vapors -> Acids, Inorganic
Physical DescriptionFound only in aqueous solution: Colorless liquid; Turns yellow on standing; [Merck Index]

Physicochemical properties

Melting point
100 ℃ · decomposes at 100℃ [CRC10]
Density
3.28 · 3.28 [HAW93]
solubility
2 O · soluble in H2O
form
stable only in aqueous solution
color
stable only in aqueous solution
Water Solubility
93 · can exist only in aq media [HAW93]

Safety & regulation

Hazard information

Hazards SummaryA strong skin, eye, and mucous membrane irritant; [Merck Index] Unstable and exists only in dilute solutions; A strong tissue irritant; [Hawley] See Bromine.

Toxicology

Treatment · 1 item

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. Bromate is also a potential carcinogen. (L625, L626, L627, L638)

Exposure RoutesOral (L96) ; inhalation (L96) ; dermal (L96)
Toxicity Summary · 1 item

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 item

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationPotassium bromate: 2B, possibly carcinogenic to humans. (L135)

Safety data

tsca
TSCA listed
ridadr
3139
hazard_class
5.1
packing_group
II

Chemistry & industry

Pharmacology

Metabolism/Metabolites · 1 item

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

Uses & manufacturing

UsesUsed as an oxidizing agent; [Merck Index] Used in dyes, intermediates, and pharmaceuticals; [Hawley]
General Manufacturing InformationBromic acid: INACTIVE

Applications

UsesOxidizing agent.

Preparation methods · 1 item

PreparationBromic acid is prepared by adding sulfuric acid to barium bromate.Ba(BrO3)2 + H2SO4 → 2HBrO3 + BaSO4The product is distilled and absorbed in water. A 50% solution may be obtained by slow evaporation of the dilute solution in vacuum at -12°C.

Upstream & downstream products

Suppliers6 total

上海参比医药科技有限公司(进口产品部)13368167990 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
湖北玖天生物医药科技有限公司027-88013699 17354350817 · [email protected]
SUZHOU SENFEIDA CHEMICAL CO.,LTD+86-0512-83500002 +86-15195660023 · [email protected]
上海宝杨宝欣生物科技有限公司021-56698539 19921169802 · [email protected]

Additional notes

DefinitionChEBI: Bromic acid is a bromine oxoacid. It is a conjugate acid of a bromate.

Related reactions

24 records

Compound notes

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