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Aluminum nitrate nonahydrate

HCID 24567
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Basic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
7784-27-2
Standard SMILES
O.O.O.O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Al+3]
InChIKey
SWCIQHXIXUMHKA-UHFFFAOYSA-N
Molecular formula
AlH18N3O18
Average molar mass
375.13 g/mol
Monoisotopic mass
375.04007437

Names & identifiers

Preferred name
Aluminum nitrate nonahydrate
IUPAC
aluminum;trinitrate;nonahydrate
English name
Aluminium nitrate nonahydrate
Molecular formula
AlH6NO4
Molecular weight
111.03

Names & synonyms

Aluminum nitrate nonahydrate7784-27-28MC6621V1HDTXSID401015755Aluminium nitrate nonahydrateRefChem:111681DTXCID401473937616-523-8Aluminum trinitrate nonahydratealuminum;trinitrate;nonahydrateMFCD00149132UNII-8MC6621V1H
Show more names
ALUMINUM NITRATE, 9-HYDRATEnitricacid,aluminumsaltnonahydrateNitricacid,alluminum nitrateALUMINIUM STANDARDAluminiumNitrateArAluminium nitrate noAlumunium Nitrate ARALUMINUM NITRATE 9H2O
ALUMINUM(III) NITRATE, NONAHYDRATE (1:3:9)AlH18N3O18Nitric acid, aluminum salt, nonahydrateSCHEMBL94579Nitric acid, aluminum salt, nonahydrate (8CI,9CI)SWCIQHXIXUMHKA-UHFFFAOYSA-NAluminium nitrate--water (1/3/9)AKOS015855259

Database identifiers

CAS
7784-27-2
PubChem CID
24567
DTXSID
DTXSID401015755
UNII
8MC6621V1H
EC Number
616-523-8

Properties

Computed structural propertiesFilling in

Topological polar surface area
198 Ų
Hydrogen bond donors
9
Hydrogen bond acceptors
18
Rotatable bonds
0
Heavy atoms
22
Formal charge
0
Complexity
18.8

Experimental & physicochemical properties

Density1.72 @25 °C
Melting Point73.5 °C

Physicochemical properties

Melting point
73 °C · 73 °C(lit.)
Boiling point
100 °C/760mmHg · 100°C/760mmHg
Density
1.25 · 1.25
bulk density
880 kg/m3 · 880kg/m3
storage temp.
5 °C · Store at +5°C to +30°C.
solubility
ethanol: very soluble(lit.)
form
Solid
color
White
PH
2 · 2.0-4.0 (50g/l, H2O, 20℃)
Water Solubility
64 g/100 · 64 g/100 mL (25 ºC)
Sensitive
Hygroscopic
Merck
14 · 14,352
Exposure limits
2 mg/m3 · NIOSH: TWA 2 mg/m3

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

GHS classification

GHS Classification · 5 items

This chemical does not meet GHS hazard criteria for 0.9% (2 of 228) of reports.

Danger

H272 (70.2%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P264, P264+P265, P280, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P332+P317, P337+P317, P362+P364, P370+P378, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 228 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 2 items

Chemical: Nitric acid, aluminium salt, nonahydrate

Aluminium nitrate nonahydrate: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesOx. Liq. 3 (70.2%)

Safety & protection

Protective Action Criteria (PAC) · 3 items

11 [mg/m3]

120 [mg/m3]

730 [mg/m3]

Safety data

PPE
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
1
tsca
Yes
rtecs
BD1050000
ridadr
UN 1438 5.1/PG 3
hs_code
28342980

Chemistry & industry

Uses & manufacturing

Household ProductsInformation on 2 consumer products that contain Aluminum nitrate nonahydrate in the following categories is provided:
Applications · 3 items

UsesThe nonahydrate and other hydrated aluminum nitrates have many applications. These salts are used to produce alumina for preparation of insulating papers, in cathode tube heating elements, and on transformer core laminates. The hydrated salts are also used for extraction of actinide elements.

UsesIt finds use in tanning leather, antiperspirant, corrosion protection, extraction of uranium, nitrating agent. It is an effective dopant for producing highly conductive thin film by utilizing the sol gel method.

UsesAluminium nitrate nonahydrate is used in metal standard solutions; extraction of uranium.

Preparation methods

PreparationThe nonahydrate is prepared by treating aluminum, aluminum hydroxide, aluminum oxide, or aluminous mineral with nitric acid. The nitrate is crystallized from the solution.

Upstream & downstream products

Upstream raw materials

Aluminum nitrateNitrogen TetroxideAluminumMercuric OxideNitric acidAluminum hydroxide

Related reactions

14 records
New reaction record
HRID 483763 reaction equation
HRID 483763As reactantuspto-grants-1993_07
HRID 638684 reaction equation
HRID 638684As reactantuspto-grants-2010_04
HRID 909951 reaction equation
HRID 909951As reactantuspto-grants-2011_09
HRID 1257483 reaction equation
HRID 1257483As reactantuspto-grants-2013_06
HRID 1257484 reaction equation
HRID 1257484As reactantuspto-grants-2013_06
HRID 1257485 reaction equation
HRID 1257485As reactantuspto-grants-2013_06
HRID 1606389 reaction equation
HRID 1606389As reactantuspto-grants-1976_04
HRID 1868566 reaction equation
HRID 1868566As reactantuspto-grants-2009_12
Page 1 of 2

Compound notes

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On this pageBasic informationNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Stability
Strong oxidizer - contact with combustible material may lead to fire. Incompatible with water, most common metals, organics. Moisture-sensitive.
InChI
1S/Al.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;
InChIKey
SWCIQHXIXUMHKA-UHFFFAOYSA-N
SMILES
O.O.O.O.O.O.O.O.O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
LogP
-0.129 · -0.129 (est)
CAS DataBase Reference
7784 · 7784-27-2(CAS DataBase Reference)
FDA UNII
8 MC6621V1H · 8MC6621V1H
UNSPSC Code
41116107 · 41116107
NACRES
24 · NB.24
Symbol(GHS)
3 · GHS03,GHS07
Signal word
Warning
Hazard statements
272 · H272-H315-H319
Precautionary statements
264 · P264-P280-P302+P352-P332+P313-P362+P364-P305+P351+P338-P337+P313
PPE
3 · Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
O,Xi,Xn
Risk Statements
8 · 8-36/38-36-22
Safety Statements
17 · 17-26-36
RIDADR
1438 · UN 1438 5.1/PG 3
WGK Germany
1 · 1
RTECS
1050000 · BD1050000
TSCA
Yes
HazardClass
5.1 · 5.1
PackingGroup
III
HS Code
28342980 · 28342980
Storage Class
13 · 13 - Non Combustible Solids
Hazard Classifications
1 · Eye Dam. 1
Toxicity
50 orally · LD50 orally in Rabbit: 3671 mg/kg
Toxicity
LD50 orally in Rabbit: 3671 mg/kg
risk_code
8-36/38-36-22
Signal word
Warning
Symbol(GHS)
GHS03,GHS07
hazard_code
O,Xi,Xn
safety_code
17-26-36
hazard_class
5.1
Storage Class
13 - Non Combustible Solids
packing_group
III
Hazard statements
H272-H315-H319
Hazard Classifications
Eye Dam. 1
Precautionary statements
P264-P280-P302+P352-P332+P313-P362+P364-P305+P351+P338-P337+P313