Basic information
- Standard SMILES
CC(C)[N-]C(C)C.[Li+]- InChIKey
ZCSHNCUQKCANBX-UHFFFAOYSA-N- Molecular formula
- C6.H14.Li.N
- Average molar mass
- 107.1 g/mol
- Monoisotopic mass
- 107.128629
Names & identifiers
- Preferred name
- Lithium diisopropylamide
- IUPAC
- lithium di(propan-2-yl)azanide
Names & synonyms
Lithium diisopropylamide4111-54-0lithiodiisopropylamine2-Propanamine, N-(1-methylethyl)-, lithium saltEINECS 223-893-0EC 223-893-0diisopropylamine lithium salt2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1)DTXSID6063305DIISOPROPYLAMINE LITHIUM SALT [MI]RefChem:799533DTXCID4039863
Show more names
2Propanamine, N(1methylethyl), lithium salt223-893-0UNII-OL028KIW1IOL028KIW1Ilithium;di(propan-2-yl)azanideC6H14LiNMFCD00064449Lithium di-isopropyl amide
Database identifiers
- CAS
4111-54-0- PubChem CID
- 2724682
- DTXSID
DTXSID6063305- UNII
- OL028KIW1I
- EC Number
- 223-893-0
- Nikkaji
- J224.914F
Properties
Computed structural properties
- Topological polar surface area
- 1 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 2
- Heavy atoms
- 8
- Formal charge
- 0
- Complexity
- 37.8
Experimental & physicochemical properties
Chemical ClassesMetals -> Organic Compounds, Metal Salts
Density0.79 @25 °C
Physical Description
Wet Solid
Solid; [Merck Index]
Safety & regulation
GHS classification
GHS Classification
Danger
H228 (15.4%): Flammable solid [Danger Flammable solids]
P210, P222, P231, P233, P240, P241, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 208 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Chemical: 2-Propanamine, N-(1-methylethyl)-, lithium salt
2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
Status: Active Update: 18-03-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/13825
2-Propanamine, N-(1-methylethyl)-, lithium salt: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryPyrophoric; Reacts with water evolving flammable gases that may spontaneously ignite; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Possible teratogen; [Sigma-Aldrich MSDS] See Diisopropylamine.
Hazard Classes and CategoriesFlam. Sol. 1 (15.4%)
Safety & protection
Protective Action Criteria (PAC)
2.5 [mg/m3]
28 [mg/m3]
170 [mg/m3]
Toxicology
Adverse EffectsDermatotoxin - Skin burns.
Chemistry & industry
Uses & manufacturing
UsesUsed as a pH adjuster (perfumes) and in organic synthesis; [Merck Index]
U.S. Production2023: 50,000 - <250,000 lb
Industry UsesIntermediate
General Manufacturing Information
Pharmaceutical and Medicine Manufacturing
2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1): ACTIVE
Related reactions
4,671 records
Linked notes
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