Basic information
- CAS
14666-78-5- Standard SMILES
CCOC(=O)OOC(=O)OCC- InChIKey
CWINGZLCRSDKCL-UHFFFAOYSA-N- Molecular formula
- C6H10O6
- Average molar mass
- 178.14 g/mol
- Monoisotopic mass
- 178.04773804
Overview
This liquid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported in a solvent slurry, water, alcohol, etc.
Names & identifiers
- Preferred name
- Diethyl peroxydicarbonate
- IUPAC
- ethoxycarbonyloxy ethyl carbonate
- English name
- Diethyl peroxydicarbonate
- Molecular formula
- C6H10O6
- Molecular weight
- 178.14
Names & synonyms
Diethyl peroxydicarbonatePeroxydicarbonic acid, diethyl esterEINECS 238-707-3DTXSID0075310EC 238-707-3DIETHYL PEROXYDICARBONATE, (<= 27% IN SOLUTION)DIETHYL PEROXYDICARBONATE, [<= 27% IN SOLUTION]RefChem:133435ETHYL PEROXYCARBONATEDIETHYL PEROXYDIFORMATEDTXCID0034772238-707-3
Show more names
Bis(ethoxyformyl) peroxideBis(ethoxycarbonyl) peroxidePeroxybis(formic acid ethyl) esterPeroxydicarbonic acid diethyl esterdiethyl peroxydicarbonate, <= 27% in solutionethoxycarbonyloxy ethyl carbonate[in solution, content ≤27%]
ethoxycarbonyloxy ethyl carbonate14666-78-5SCHEMBL374891AKOS0062801801,1'-[Peroxybis(carbonyloxy)]diethaneNS00003373
Database identifiers
- CAS
14666-78-5- PubChem CID
- 61756
- DTXSID
DTXSID0075310- EC Number
- 238-707-3
- Nikkaji
- J241.342F
Properties
Computed structural properties
- XLogP
- 1.7
- Topological polar surface area
- 71.1 Ų
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 6
- Rotatable bonds
- 7
- Heavy atoms
- 12
- Formal charge
- 0
- Complexity
- 136
Experimental & physicochemical properties
Physical DescriptionThis liquid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported in a solvent slurry, water, alcohol, etc.
Physicochemical properties
- Boiling point
- 230.35 °C · 230.35°C (rough estimate)
- Density
- 1.3253 · 1.3253 (rough estimate)
- refractive index
- 1.586 · 1.5860 (estimate)
- EPA Substance Registry System
- Peroxydicarbonic acid, diethyl ester (14666-78-5)
- Symbol(GHS)
- 2 · GHS02,GHS07
- Signal word
- Danger
- Hazard statements
- 226 · H226-H242-H315-H319
- Precautionary statements
- 210 · P210-P233-P240-P241-P242-P243-P280-P234-P235-P264-P303+P361+P353-P370+P378-P302+P352-P332+P313-P362+P364-P305+P351+P338-P337+P313-P403+P235-P403-P410-P411-P420-P501
- RIDADR
- 3115 · 3115
- HazardClass
- 5.2 · 5.2
- PackingGroup
- II
- REACH Registrations
- Active
Safety & regulation
GHS classification
GHS Classification
Danger
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P234, P235, P240, P241, P242, P243, P264, P264+P265, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P235, P410, P411, P420, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 8 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazard information
Regulatory Information
Chemical: Peroxydicarbonic acid, diethyl ester
Status: Active Update: 27-05-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/13297
DOT LabelOrganic Peroxide
Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity Profile
DIETHYL PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10 °C owing to self-accelerating exothermic decomposition. Several explosions were due to shock, heat or friction. Amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry.
DOT Hazard Classification
Diethyl peroxydicarbonate, with more than 27 percent in solution
Forbidden explosives/materials (49 eCFR § 173.54/§ 173.21)
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and CategoriesFlam. Liq. 3 (100%)
Safety & protection
Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Safety data
- ridadr
- 3115
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS07
- hazard_class
- 5.2
- packing_group
- II
- Hazard statements
- H226-H242-H315-H319
- REACH Registrations
- Active
- Precautionary statements
- P210-P233-P240-P241-P242-P243-P280-P234-P235-P264-P303+P361+P353-P370+P378-P302+P352-P332+P313-P362+P364-P305+P351+P338-P337+P313-P403+P235-P403-P410-P411-P420-P501
Chemistry & industry
Applications
General DescriptionDiethyl peroxydicarbonate is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. Diethyl peroxydicarbonate is generally stored or transported in a solvent slurry, water, alcohol, etc.
Suppliers4 total
陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]
Related reactions
4 records
Compound notes
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