N-Methylformanilide

HCID 66737CAS 93-61-8
Substructure searchFind similar structures

Basic information

Standard SMILES
CN(C=O)c1ccccc1
InChIKey
JIKUXBYRTXDNIY-UHFFFAOYSA-N
Molecular formula
C8H9NO
Average molar mass
135.16 g/mol
Monoisotopic mass
135.06841391

Names & identifiers

Preferred name
N-Methylformanilide
IUPAC
N-methyl-N-phenylformamide
English name
N-Methylformanilide
Molecular formula
C8H9NO
Molecular weight
135.16

Names & synonyms

N-MethylformanilideFormamide, N-methyl-N-phenyl-AI3-12081EINECS 202-262-3DTXSID0059089NFormylNmethylanilineNMethylNformylanilineFormanilide, NmethylNMethylNphenylformamideNPhenylNmethylformamideFormamide, NmethylNphenylRefChem:163826
Show more names
N-MethylforManilidNSC 3828formaniLMETHYLFORMANILIDEN-methylform anilineMethylphenylformamideN-METHYL-N-FORMANILIDE
Formanilide, Nmethyl (8CI)DTXCID1048839202-262-3JIKUXBYRTXDNIY-UHFFFAOYSA-N93-61-8N-Methyl-N-phenylformamideN-Formyl-N-methylanilineFormanilide, N-methyl-

Database identifiers

CAS
93-61-8
PubChem CID
66737
DTXSID
DTXSID0059089
UNII
3D8E5U4HSE
EC Number
202-262-3
Nikkaji
J3.078.215A、J37.681G

Properties

Computed structural properties

XLogP
1.1
Topological polar surface area
20.3 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
1
Rotatable bonds
1
Heavy atoms
10

Experimental & physicochemical properties

Chemical ClassesNitrogen Compounds -> Other Aromatics (Nitrogen)
Vapor Pressure0.02 [mmHg]
Physical DescriptionColorless liquid; mp = 9-13 deg C; [Alfa Aesar MSDS]

Physicochemical properties

Melting point
8 · 8-13 °C (lit.)
Boiling point
243 · 243-244 °C (lit.)
Density
1.095 g/mL · 1.095 g/mL at 25 °C (lit.)
vapor pressure
2.66 Pa · 2.66 Pa (25 °C)
refractive index
20 · n20/D 1.561(lit.)
Flash point
260 °F · 260 °F

Safety & regulation

GHS classification

GHS Classification · 4 items

Warning

H302 (88.3%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 60 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 3 items

Chemical: Formamide, N-methyl-N-phenyl-

Status: Active Update: 05-12-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/18619

N-Methylformanilide: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS] See N-Phenylformamide.
Hazard Classes and CategoriesAcute Tox. 4 (88.3%)

Safety data

PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
2
tsca
TSCA listed
hs_code
29242995
risk_code
22-43-38
Signal word
Warning

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationFormamide, N-methyl-N-phenyl-: ACTIVE
Applications · 2 items

UsesOrganic synthesis.

UsesN-Methylformanilide is used as a formylating reagent for certain organometallics. It is in combination with phosphoryl chloride used for Vilsmeier-Haack reactions and in heterocycle syntheses. Further, it acts as a swelling agent in the dyeing process of meta-aramid fibers.

Upstream & downstream products

Suppliers50 total

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]

Related reactions

165 records
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Linked notes

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