Acetic acid, azido-, ethyl ester (HCID 69480)

Names & identifiers

Preferred name: Acetic acid, azido-, ethyl ester
IUPAC: ethyl 2-azidoacetate
English name: Ethyl Azidoacetate
Molecular formula: C4H7N3O2
Molecular weight: 129.12

Names & synonyms

Ethyl azidoacetate637-81-0Azidoacetic acid ethyl esterAcetic acid, azido-, ethyl esterCCRIS 3368EINECS 211-301-3BRN 4247209DTXSID30213101NSC 84132RefChem:316550DTXCID90135592211-301-3

Show more names

azidoacetateazido-aceticaciethylesterDDYSYZETHYL AZIDOACETETHYLAZIDACETATEEthyl azidacetate 97%Cefazolin Impurity 37ethyl 2-azidoethanoate

Ethyl 2-azidoacetateAzido-acetic acid ethyl esterMFCD00190177Acetic acid, 2-azido-, ethyl esterEthylazidoacetateethyl azido-acetateethyl-2-azidoacetateethyl alpha-azidoacetate

Database identifiers

CAS: 637-81-0
PubChem CID: 69480
DTXSID: DTXSID30213101
EC Number: 211-301-3
Nikkaji: J205.911H

Properties

Computed structural properties

XLogP: 1.6
Topological polar surface area: 40.7 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 4
Rotatable bonds: 4
Heavy atoms: 9
Formal charge: 0
Complexity: 139

Physicochemical properties

Boiling point: 44 · 44-46°C 2mm
Density: 1.12 g/ml · 1.12g/ml
refractive index: 1.433 to · 1.4330 to 1.4370
Flash point: 25 °C · 25 °C
storage temp.: Refrigerator, under inert atmosphere
solubility: Chloroform (Sparingly), Ethyl Acetate (Slightly)
form: Oil
color: Colourless to Pale Yellow
BRN: 4247209 · 4247209
InChI: InChI=1S/C4H7N3O2/c1-2-9-4(8)3-6-7-5/h2-3H2,1H3
InChIKey: HVJJYOAPXBPQQV-UHFFFAOYSA-N
SMILES: C(=O)(OCC)CN=[N+]=[N-]
CAS DataBase Reference: 637 · 637-81-0(CAS DataBase Reference)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 7 · GHS07,GHS08
Signal word: Warning
Hazard statements: 315 · H315-H319-H336-H351
Precautionary statements: 201 · P201-P302+P352-P305+P351+P338-P308+P313
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: Xn,Xi,C,F
Risk Statements: 1 · 1-40-36/37/38-10-67-65-63-48/20-38-11
Safety Statements: 7 · 7-16-26-35-36-47-62-45-36/37
RIDADR: 1593 · UN 1593 6.1/PG 3
WGK Germany: 2 · 2
Hazard Note: Irritant/Corrosive
HS Code: 2929.9 · 2929.90.5090
HazardClass: 3 · 3
PackingGroup: III
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 2 Flam · Eye Irrit. 2Flam. Liq. 2
Limited Quantities: 5 L · 5.0 L (1.3 gallons) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Safety & regulation

GHS classification

GHS Classification · 4 items

Warning

H226 (90.5%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 21 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Hazard Classes and CategoriesFlam. Liq. 3 (90.5%)

Safety data

PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 2
ridadr: UN 1593 6.1/PG 3
hs_code: 2929.90.5090
risk_code: 1-40-36/37/38-10-67-65-63-48/20-38-11
Signal word: Warning
Symbol(GHS): GHS07,GHS08
hazard_code: Xn,Xi,C,F
hazard_note: Irritant/Corrosive
safety_code: 7-16-26-35-36-47-62-45-36/37
hazard_class: 3
Storage Class: 3 - Flammable liquids
packing_group: III
Hazard statements: H315-H319-H336-H351
Limited Quantities: 5.0 L (1.3 gallons) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2
Precautionary statements: P201-P302+P352-P305+P351+P338-P308+P313

Chemistry & industry

Applications · 1 item

UsesEthyl Azidoacetate is an important organic substance that can undergo cyclisation reactions and is commonly used in the field of chemical synthesis.The condensation of 1-methyl-β-carboline-3-carbaldehyde with ethyl azidoacetate can be used to prepare 2-formylxanthine derivatives[1].

Upstream & downstream products

Downstream products

(4-Methoxy-1H-pyrrolo[2,3-b]pyridin-2-yl)methanol 2-(4-Methoxy-1H-pyrrolo[2,3-b]pyridin-2-yl)ethanamine 4-Methoxy-1H-pyrrolo[2,3-b]pyridine-2-carbaldehyde Ethyl 4-methoxy-1H-pyrrolo[2,3-b]pyridine-2-carboxylate ethyl 6-bromo-4-fluoro-1H-indole-2-carboxylate Ethyl 6H-furo[2,3-b]pyrrole-5-carboxylate 2-(4-Methoxyphenyl)-4H-furo[3,2-b]pyrrole-5-carboxylic Acid Ethyl Ester

Suppliers50 total

南京波普生物医药研发有限公司025-87138562 18951783565 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

济南杰诚生物科技有限公司18669572301 · [email protected]

合肥翰刚医药科技有限公司+8618062405514 · [email protected]

山东海舟生物工程有限公司130-0567-0367 13006570367 · [email protected]

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Linked notes

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Basic information