HuagongsheHuagongshe Chemistry Print Report · For research reference only
Butanediol diacrylate
BDDA · 1,4-Butylene diacrylate · Butane-1,4-diyl diacrylate · 1,4-butylenediacrylate · Tetramethylene acrylate · 1,4-BIS(ACRYLOYLOXY)BUTANE · sr213 · butylenediacrylate
Identifiers & Physical Properties
| CAS No. | 1070-70-8 |
|---|---|
| Molecular formula | C10H14O4 |
| Average molar mass | 198.22 g/mol |
| Monoisotopic mass | 198.08920893 g/mol |
| SMILES | C=CC(=O)OCCCCOC(=O)C=C |
| InChIKey | JHWGFJBTMHEZME-UHFFFAOYSA-N |
| PubChem CID | 70613 |
| ChEMBL | CHEMBL3182145 |
| EC No. | 213-979-6 |
| DTXSID | DTXSID6044779 |
Chemical & Physical Properties
| XLogP | 1.9 |
|---|---|
| Topological polar surface area | 52.6 |
| Hydrogen bond donors | 0 |
| Hydrogen bond acceptors | 4 |
| Rotatable bonds | 9 |
| Heavy atoms | 14 |
| Formal charge | 0 |
| Complexity | 196 |
| Physical Description | Liquid |
| Melting point | -7°C |
| Boiling point | 83 °C/0.3 mmHg (lit.) |
| Density | 1.051 g/mL at 25 °C (lit.) |
| Vapor pressure | 0.83 hPa (80 °C) |
| Refractive index | n20/D 1.456(lit.) |
| Flash point | >230 °F |
| Storage conditions | 2-8°C |
| Solubility | 16.3g/lImmiscible with water. |
| Physical state | Liquid |
| Color | Colorless |
| Specific gravity | 1.055-1.105 |
| Explosive limits | 1.3-7%(V) |
| Viscosity | 8 cp (25C) |
| InChI | 1S/C10H14O4/c1-3-9(11)13-7-5-6-8-14-10(12)4-2/h3-4H,1-2,5-8H2 |
| InChIKey | JHWGFJBTMHEZME-UHFFFAOYSA-N |
| SMILES | C=CC(=O)OCCCCOC(=O)C=C |
| LogP (partition coefficient) | 1.9 at 23℃ |
| CAS DataBase Reference | 1070-70-8(CAS DataBase Reference) |
| EWG's Food Scores | 2 |
| FDA UNII | 53P6JR1A3R |
| EPA Substance Registry System | 1,4-Butanediol diacrylate (1070-70-8) |
| UNSPSC Code | 12162002 |
| NACRES | NA.23 |
| GHS pictogram | GHS05,GHS06 |
| Signal word | Danger |
| GHS hazard statements | H302+H332-H311-H314-H317-H412 |
| GHS precautionary statements | P273-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard symbols | C |
| Risk statements (R) | 21-34-43-23 |
| Safety statements (S) | 26-36/37/39-45 |
| UN transport number | UN 1760 8/PG 2 |
| Water hazard class (WGK) | 1 |
| RTECS number | UD3130000 |
| Autoignition temperature | 285 °C |
| TSCA inventory status | TSCA listed |
| Customs code | 2916 12 00 |
| Hazard class | 8Acute Tox. 3 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Skin Corr. 1BSkin Sens. 1A |
| Packing group | II |
| Storage class | 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials |
| Toxicity | mouse,LD50,oral,1gm/kg (1000mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 86, 1990. |
| REACH registrations | Active |
Safety & Regulations
| GHS classification | DangerH312: Harmful in contact with skin [Warning Acute toxicity, dermal]P260, P261, P264, P272, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P333+P317, P362+P364, P363, P405, and P501 (click each P-code to see the statement)H302 (59.2%): Harmful if swallowed [Warning Acute toxicity, oral]P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P330, P333+P317, P337+P317, P361+P364, P362+P364, P363, P405, and P501 (click each P-code to see the statement) |
|---|---|
| Regulatory information | Chemical: Poly(oxy-1,4-butanediyl), .alpha.-(1-oxo-2-propenyl)-.omega.-[(1-oxo-2-propenyl)oxy]-Chemical: 2-Propenoic acid, 1,4-butanediyl ester2-Propenoic acid, 1,1'-(1,4-butanediyl) ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 1,1'-(1,4-butanediyl) ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)FRI - indicates a polymeric substance containing no free-radical initiator in its Inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used.Status: Active Update: 22-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/252141,4-Butanediol diacrylate: Does not have an individual approval but may be used under an appropriate group standard |
| Hazard Classes and Categories | Acute Tox. 4 (59.2%)Skin Irrit. 2 (100%)Acute toxicity - category 4Acute Tox. 4 * |
| Water hazard class (WGK) | 1 |
| TSCA inventory status | TSCA listed |
| RTECS number | UD3130000 |
| UN transport number | UN 1760 8/PG 2 |
| Customs code | 2916 12 00 |
| Toxicity | mouse,LD50,oral,1gm/kg (1000mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 86, 1990. |
| Risk statements (R) | 21-34-43-23 |
| Signal word | Danger |
| GHS pictogram | GHS05,GHS06 |
| Hazard symbols | C |
| Safety statements (S) | 26-36/37/39-45 |
| Hazard class | 8Acute Tox. 3 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Skin Corr. 1BSkin Sens. 1A |
| Storage class | 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials |
| Packing group | II |
| GHS hazard statements | H302+H332-H311-H314-H317-H412 |
| REACH registrations | Active |
| Autoignition temperature | 285 °C |
| GHS precautionary statements | P273-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
Applications & Uses
Description
A positive patch test was observed in a male process worker in a paint factory, sensitized to an epoxy diacrylate (1,4-butanediol diacrylate) contained in raw materials of UV -light-curable paint. The positive reaction was probably due to a cross reactivity.
Uses
cross-linking monomer for use in inks, adhesives, textile product modifiers, photo resists, etc.
Uses
1,4-Butanediol diacrylate is used as a multifunctional crosslinker. It is used in drying technology for paintings, coatings, inks, resins and adhesives. It serves as an intermediate product for polymer synthesis in the chemical industry.
Uses
1,4-Butanediol diacrylate may be used as a multifunctional crosslinker.