2-Bromoethyl methyl ether (HCID 80972)

Names & identifiers

Preferred name: 2-Bromoethyl methyl ether
IUPAC: 1-bromo-2-methoxyethane
English name: 1-Bromo-2-methoxyethane
Molecular formula: C3H7BrO
Molecular weight: 138.99

Names & synonyms

1-Bromo-2-methoxyethane2-Bromoethyl methyl ether6482-24-2Ethane, 1-bromo-2-methoxy-2-Methoxyethyl bromideEther, 2-bromoethyl methyl2-bromo-1-methoxyethanebromoethyl methyl etherQMC9NTS6GR2-methoxy-1-bromoethaneEINECS 229-339-4NSC 81806

Show more names

Methoxyethyl bromide2-Bromoethyl methyl etheTIMTEC-BB SBB0079061-METHOXY-2-BROMOETHANE1-bromo-2-methoxy-ethan

NSC-81806(2-METHOXY)BROMOETHANEDTXSID0064385YZUPZGFPHUVJKC-UHFFFAOYSA-.BETA.-METHOXYETHYL BROMIDE1Bromo2methoxyethane2methoxyethyl bromideEthane, 1bromo2methoxy

Database identifiers

CAS: 6482-24-2、9037-24-5
PubChem CID: 80972
DTXSID: DTXSID0064385
UNII: QMC9NTS6GR
EC Number: 229-339-4
Nikkaji: J208.123G

Properties

Computed structural properties

XLogP: 0.8
Topological polar surface area: 9.2 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 1
Rotatable bonds: 2
Heavy atoms: 5
Formal charge: 0
Complexity: 16

Experimental & physicochemical properties

Physical DescriptionColorless or pale yellow liquid; [Alfa Aesar MSDS]

Kovats Retention Index696；716.2

Physicochemical properties

Boiling point: 40 · 40-41 °C/66 mmHg (lit.)
Density: 1.479 g/mL · 1.479 g/mL at 25 °C (lit.)
refractive index: 20 · n20/D 1.447(lit.)
Flash point: 83 °F · 83 °F
storage temp.: 2 · 2-8°C
solubility: 14.4 g/L · water: soluble14.4g/L at 25°C
form: Liquid
Specific Gravity: 1.479 · 1.479
color: Clear colorless to yellow
Water Solubility: 14 · Soluble in water.14,4 g/L at 25°C
InChI: InChI=1S/C3H7BrO/c1-5-3-2-4/h2-3H2,1H3
InChIKey: YZUPZGFPHUVJKC-UHFFFAOYSA-N
SMILES: C(Br)COC
CAS DataBase Reference: 6482 · 6482-24-2(CAS DataBase Reference)
FDA UNII: 9 NTS6GR · QMC9NTS6GR
NIST Chemistry Reference: 1 · Ethane, 1-bromo-2-methoxy(6482-24-2)
EPA Substance Registry System: 1 · Ethane, 1-bromo-2-methoxy- (6482-24-2)
UNSPSC Code: 12352100 · 12352100
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS06
Signal word: Danger
Hazard statements: 226 · H226-H301-H315-H319-H335
Precautionary statements: 210 · P210-P301+P310+P330-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: Xi,F,Xn
Risk Statements: 10 · 10-36/37/38-22
Safety Statements: 16 · 16-26-37/39
RIDADR: 3271 · UN 3271 3/PG 3
WGK Germany: 3 · 3
Hazard Note: Irritant/Flammable
TSCA: TSCA listed
HazardClass: 3 · 3
PackingGroup: III
HS Code: 29091990 · 29091990
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 3 OralEye · Acute Tox. 3 OralEye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
Limited Quantities: 1 L · 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Safety & regulation

GHS classification

GHS Classification · 5 items

Danger

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H301 (83.7%): Toxic if swallowed [Danger Acute toxicity, oral]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (98%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 49 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Hazards SummaryA skin and strong eye irritant; A lachrymator; [Alfa Aesar MSDS] See beta-Chloroethyl methyl ether.

Peroxide Forming Chemical · 3 items

2-Bromoethyl methyl ether

D: Other compounds that may form peroxides

Kelly

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Acute Tox. 3 (83.7%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (98%)

Toxicology

Adverse EffectsLacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears.

Safety data

PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 3
tsca: TSCA listed
ridadr: UN 3271 3/PG 3
hs_code: 29091990
risk_code: 10-36/37/38-22
Signal word: Danger
Symbol(GHS): GHS02,GHS06
hazard_code: Xi,F,Xn
hazard_note: Irritant/Flammable
safety_code: 16-26-37/39
hazard_class: 3
Storage Class: 3 - Flammable liquids
packing_group: III
target organs: Respiratory system
Hazard statements: H226-H301-H315-H319-H335
Limited Quantities: 1.0 L (0.3 gallon) (liquid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Hazard Classifications: Acute Tox. 3 OralEye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
Precautionary statements: P210-P301+P310+P330-P302+P352-P305+P351+P338

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationEthane, 1-bromo-2-methoxy-: ACTIVE

Applications · 3 items

Uses2-Bromoethyl methyl ether has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.

Uses1-Bromo-2-methoxyethane has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.

General DescriptionKinetics of potassium iodide exchange reaction with 2-bromoethyl methyl ether in acetone at 15 and 25°C has been investigated.

Upstream & downstream products

Upstream raw materials

Downstream products

N-(2-METHOXYETHYL)ETHYLAMINE N-(2-METHOXYETHYL)METHYLAMINE 1-(2-Methoxyethyl)piperazine 1-(2-Methoxyethyl)hydrazine 1,4-DIMETHOXYBUTANE Erlotinib 1-(2-Methoxyethyl)-4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole PENTAETHYLENE GLYCOL MONOMETHYL ETHER Tris(2-(2-methoxyethoxy)ethyl)amine (2-Methoxyethyl)benzene 3-broMo-5-(2-Methoxyethoxy)pyridine 2-bromo-5-(2-methoxyethoxy)pyridine

Suppliers50 total

江西益众化工有限公司15307925109 15350027073 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

湖北永阔科技有限公司027-59223108 15972152991 · [email protected]

湖北万得化工有限公司15377098680 15377098680 · [email protected]

上海腾准生物科技有限公司19821570922 · [email protected]

Related reactions

1,486 records

New reaction record

HRID 5371As reactantuspto-grants-1993_09

HRID 8868As reactantuspto-grants-2006_08

HRID 9200As reactantuspto-grants-2006_08

HRID 11926As reactantuspto-grants-2006_08

HRID 11938As reactantuspto-grants-2006_08

HRID 18541As reactantuspto-grants-2010_06

HRID 18556As reactantuspto-grants-2010_06

HRID 18596As reactantuspto-grants-2010_06

Linked notes

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Basic information