CAS 7688-51-9 N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine (HCID 82125)

Names & identifiers

Preferred name: N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
IUPAC: N,N-bis(trimethylsilyl)prop-2-en-1-amine
English name: N-Allyl-n N-bis(trimethylsilyl)amine
Molecular formula: C9H23NSi2
Molecular weight: 201.46

Names & synonyms

7688-51-9N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamineEINECS 231-699-2DTXSID50227684Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-RefChem:828934DTXCID00150175231-699-2N,N-Bis(trimethylsilyl)allylamineN-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINEN,N-bis(trimethylsilyl)prop-2-en-1-amineN-Allyl-N,N-bis(trimethylsilyl)amine

Show more names

Ditrimethylsilyl allylamineN,N'-bis(trimethylsilyl)allylamineProp-2-en-1-ylbis(trimethylsilyl)amineN-Allyl-N,N-bis(trimethylsilyl)amine 97%2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&

3-Bis(trimethylsilyl)amino-1-propene(prop-2-en-1-yl)bis(trimethylsilyl)amineMFCD00545193N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamineC9H23NSi2Allylbis(trimethylsilyl)amine578932_ALDRICH, EINECS 231-699-2, MolPort-003-937-319, N,N-Bis(trimethylsilyl)allylamine, CID82125, N-Allyl-N,N-bis(trimethylsilyl)amine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine, Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-, 7688-51-9AHL726ZXM9

Database identifiers

CAS: 7688-51-9
PubChem CID: 82125
DTXSID: DTXSID50227684
UNII: AHL726ZXM9
EC Number: 231-699-2
Nikkaji: J125.864H

Properties

Computed structural properties

Topological polar surface area: 3.2 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 1
Rotatable bonds: 4
Heavy atoms: 12
Formal charge: 0
Complexity: 139

Physicochemical properties

Boiling point: 72 °C/15 · 72 °C/15 mmHg (lit.)
Density: 0.816 g/mL · 0.816 g/mL at 25 °C (lit.)
refractive index: 20 · n20/D 1.440(lit.)
Flash point: 109 °F · 109 °F
form: liquid
Specific Gravity: 0.817 · 0.817
Hydrolytic Sensitivity: 8 · 8: reacts rapidly with moisture, water, protic solvents
InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChIKey: CVNCFZIIZGNVFD-UHFFFAOYSA-N
SMILES: C[Si](C)(C)N(CC=C)[Si](C)(C)C
UNSPSC Code: 12352103 · 12352103
NACRES: 22 · NA.22
Symbol(GHS): 2 · GHS02,GHS07
Signal word: Warning
Hazard statements: 226 · H226-H315-H319-H335
Precautionary statements: 210 · P210-P302+P352-P305+P351+P338
target organs: Respiratory system
PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes: Xi
Risk Statements: 10 · 10-36/37/38
Safety Statements: 16 · 16-26-36/37
RIDADR: 1993 · UN 1993 3/PG 3
WGK Germany: 3 · 3
TSCA: TSCA listed
Storage Class: 3 · 3 - Flammable liquids
Hazard Classifications: 2 Flam · Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3

Safety & regulation

GHS classification

GHS Classification · 5 items

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Regulatory Information · 2 items

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)

Regulatory information

Regulatory Information · 2 items

Chemical: Silanamine, 1,1,1-trimethyl-N-2-propenyl-N-(trimethylsilyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Safety data

PPE: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
risk_code: 10-36/37/38
Signal word: Warning
Symbol(GHS): GHS02,GHS07
hazard_code: Xi
safety_code: 16-26-36/37
Storage Class: 3 - Flammable liquids
target organs: Respiratory system
Hazard statements: H226-H315-H319-H335
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
Precautionary statements: P210-P302+P352-P305+P351+P338

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationSilanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)-: ACTIVE

Applications · 1 item

UsesN-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.