1-Bromohexane → 1-Ethynyl-2-(2-ethylhexyl)naphthalene

Reaction equation

[C:1]([C:3]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:6]=[CH:5][C:4]=1[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])#[CH:2].Br[CH2:20][CH2:21]CCCC.BrCC(CC)CCCC>>[C:1]([C:3]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[CH:6]=[CH:5][C:4]=1[CH2:13][CH:14]([CH2:20][CH3:21])[CH2:15][CH2:16][CH2:17][CH3:18])#[CH:2]

Participants

Reactant 3

HCID 81011-Bromohexane

HCID 868042-Ethylhexyl bromide

HCID 21954826HCID 21954826, compound

Product 1

HCID 866349761-Ethynyl-2-(2-ethylhexyl)naphthalene

Procedure

1-Ethynyl-2-(2-ethylhexyl)naphthalene was prepared in a similar manner to 1-ethynyl-2-hexylnaphthalene, except that bromohexane was replaced by 1-bromo-2-ethylhexane.

Sources & evidence

ORD record: ord-220103cca55842b48111fcde0d0abaa3
Source dataset: uspto-grants-2011_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07977441B2

Reaction notes

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