Benzaldehyde → HCID 10443568, compound

HRID 1016715

Reaction equation

HRID 1016715 reaction equation
C[CH:2]([NH2:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH:9](=O)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[H][H].[CH3:19]O>[Pd]>[CH2:9]([NH:8][CH2:2][CH:3]([CH3:19])[CH2:4][CH2:5][CH2:6][CH3:7])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

6

Reactant 4

HCID 240BenzaldehydeHCID 887MethanolHCID 56032-AminoheptaneHCID 178418361HCID 178418361, compound

Product 1

HCID 10443568HCID 10443568, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

100 ml of methanol and 100 mmol of 2-heptylamine are initially taken and 100 mmol of benzaldehyde are added dropwise at 24° C. in the course of 15 minutes. Stirring is effected for 6 hours at 24° C., the completeness of the iminization is checked by GC, 0.5 g of Pd/C (10% by weight) is added and the crude mixture is hydrogenated with hydrogen for 5 hours at atmospheric pressure. A sample is taken and the composition is investigated by GC analysis.

Workup

  1. additionis added

Sources & evidence

ORD record
ord-ba1edca4717347c4aa02c2f111f30d6f
Source dataset
uspto-grants-2002_11
Patent number
US06476268B1

Linked notes

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