Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1068520

Reaction equation

C(N(CCCC)CCCC)CCC.[CH2:14](Cl)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[Cl:22][SiH:23]([Cl:25])[Cl:24]>>[CH2:14]([Si:23]([Cl:25])([Cl:24])[Cl:22])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

Reactant 3

HCID 7503Benzyl Chloride

HCID 7622Tributylamine

HCID 24811Trichlorosilane

Product 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-Yield 29%

Procedure

In the same apparatus and procedure as Example 1 above, 0.090 g (0.5 mmol) of tri-n-butylamine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 150° C. for 6 hrs. The resulting mixture was distilled to give 0.32 g of benzyltrichlorosilane (yield; 29%).

Workup

distillationThe resulting mixture was distilled

Sources & evidence

ORD record: ord-fdbd087bf1b8404682147f6309557694
Source dataset: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06251057B1

Linked notes

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