Triethylamine → 1,3-Bis(trichlorosilyl)propane

HRID 1068532

Reaction equation

HRID 1068532 reaction equation
C(N(CC)CC)C.Cl[CH2:9][CH2:10][CH2:11]Cl.[Cl:13][SiH:14]([Cl:16])[Cl:15]>>[Cl:13][Si:14]([Cl:16])([Cl:15])[CH2:9][CH2:10][CH2:11][Si:14]([Cl:16])([Cl:15])[Cl:13]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 88811,3-DichloropropaneHCID 24811Trichlorosilane

Product 1

HCID 112438561,3-Bis(trichlorosilyl)propaneYield 9%

Procedure

In the same apparatus and procedure as Example 1 above, 0.048 g (0.47 mmol) of triethylamine, 0.6 g (4.7 mmol) of 1,3-dichloropropane, and 3.18 g (23.5 mmol) of trichlorosilane were reacted at 200° C. for 15 hrs. The resulting mixture was distilled to give 0.13 g of 1,3-bis(trichlorosilyl)propane (yield; 9%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-557893ce53c2404b9451f329735f3300
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Linked notes

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