2-Bromoanisole → 1,1'-Biphenyl, ethenyl-

Reaction equation

Br[C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[CH2:7])=[CH:4][CH:3]=1.Br[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1OC>>[CH:6]([C:5]1[CH:8]=[CH:9][CH:2]=[CH:3][C:4]=1[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)=[CH2:7]

Participants

Reactant 2

HCID 113582-Bromoanisole

HCID 162634-Bromostyrene

Product 1

HCID 1473241,1'-Biphenyl, ethenyl-

Procedure

A vinylbiphenyl polymer was prepared in the same manner as in Example 10 except that poly-p-bromostyrene obtained as in Example 10 by using p-bromostyrene instead of p-chlorostyrene, and o-bromoanisol were used. The polymer gave a peak of OCH3 through 1H-NMR measurement in the same manner as in Example 10.

Workup

customobtained as in Example 10
customThe polymer gave a peak of OCH3 through 1H-NMR measurement in the same manner as in Example 10

Sources & evidence

ORD record: ord-aae470b2fb49450586da9e478acc1a18
Source dataset: uspto-grants-1992_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05082358

Reaction notes

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