Acetate → 2-(o-Tolyl)pyridine

HRID 1151677

Reaction equation

HRID 1151677 reaction equation
[C:49]([PH+:50]([C:51]([CH3:52])([CH3:53])[CH3:54])[C:55]([CH3:56])([CH3:57])[CH3:58])([CH3:59])([CH3:60])[CH3:61].[Cl:1][c:2]1[cH:3][cH:4][cH:5][cH:6][n:7]1.[F-:18].[K+:19].[O-:63][C:64]([CH3:65])=[O:66].[O-:67][C:68]([CH3:69])=[O:70].[O:71]1[CH2:72][CH2:73][CH2:74][CH2:75]1.[Pd+2:62].[c:20]1([CH3:21])[cH:22][cH:23][c:24]([B-:25]([c:26]2[cH:27][cH:28][c:29]([CH3:30])[cH:31][cH:32]2)([c:33]2[cH:34][cH:35][c:36]([CH3:37])[cH:38][cH:39]2)[c:40]2[cH:41][cH:42][c:43]([CH3:44])[cH:45][cH:46]2)[cH:47][cH:48]1.[c:8]1([CH3:17])[c:9]([B:14]([OH:15])[OH:16])[cH:10][cH:11][cH:12][cH:13]1>>[c:2]1(-[c:9]2[c:8]([CH3:17])[cH:13][cH:12][cH:11][cH:10]2)[cH:3][cH:4][cH:5][cH:6][n:7]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium CationHCID 79772-ChloropyridineHCID 8028TetrahydrofuranHCID 28179Fluoride IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27332672-Methylphenyl boronic acidHCID 4060964Tri-t-butylphosphoniumHCID 4608326Tetrakis(4-methylphenyl)boranuide

Product 1

HCID 825102-(o-Tolyl)pyridine

Sources & evidence

ORD record
ord-0e51b172f6e54a9fa774ecc8209f40dc
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Linked notes

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