Chlorosuccinimide → N-(Dodecylsulfonyl)-2-(chloronitromethylene)-tetrahydro-2H-1,3-thiazine
Reaction equation
[CH2:1]([S:13]([N:16]1[CH2:21][CH2:20][CH2:19][S:18][C:17]1=[CH:22][N+:23]([O-:25])=[O:24])(=[O:15])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Cl:26]N1C(=O)CCC1=O>>[CH2:1]([S:13]([N:16]1[CH2:21][CH2:20][CH2:19][S:18][C:17]1=[C:22]([Cl:26])[N+:23]([O-:25])=[O:24])(=[O:14])=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]Participants
3
Procedure
was prepared, as a yellow solid, m.p.: 76°-77° C., by treating (3A) with N-chlorosuccinimide according to the procedure described in Example 2.
Workup
- customwas prepared, as a yellow solid, m.p.: 76°-77° C.
Sources & evidence
- ORD record
- ord-14401ae62fa24eeca815555e1f226a9d