Azobisisobutyronitrile → Styrene glycidyl Methacrylate

HRID 1166408Notes

Reaction equation

HRID 1166408 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH2:15][CH:16]1[O:18][CH2:17]1)(=[O:13])[C:10]([CH3:12])=[CH2:11].N(C(C)(C)C#N)=NC(C)(C)C#N>C1(C)C=CC=CC=1>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH2:15][CH:16]1[O:18][CH2:17]1)(=[O:13])[C:10]([CH3:12])=[CH2:11]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7501StyreneHCID 7837Glycidyl methacrylate

Product 1

HCID 21867792Styrene glycidyl Methacrylate

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

The same four-necked flask as used in Example 1 was charged with 100 g of toluene, and the temperature was adjusted to 80° C. with stirring under nitrogen. Then, 120 g of styrene, 89 g of glycidyl methacrylate and 0.1 g of azobisisobutyronitrile were added thereto and the reaction carried out in the same manner as in Example 1 to give a styrene-glycidyl methacrylate copolymer. This copolymer (96 weight parts) and 4 weight parts of 4,4′-bisazidobenzal(4-methyl)cyclohexanone were dissolved in 100 weight parts of xylene and the solution was subjected to polymerization in the same manner as in Example 1, whereupon an over coat film was obtained.

Workup

  1. customwas adjusted to 80° C.

Sources & evidence

ORD record
ord-a6513315a0884485aafab8d4df47f1db
Source dataset
uspto-grants-2003_09
Patent number
US06613855B1

Reaction notes

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