1-Nitropropane → HCID 58434562, compound

HRID 1193015Notes

Reaction equation

HRID 1193015 reaction equation
[N+:1]([CH2:4][CH2:5][CH3:6])([O-:3])=[O:2].CO[CH:9]([O:15]C)[CH2:10][CH2:11][CH2:12][CH:13]=O>CCOC(C)=O.CCCCCC>[N+:1](/[C:4](/[CH2:5][CH3:6])=[CH:13]/[CH2:12][CH2:11][CH2:10][CH:9]=[O:15])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 79031-NitropropaneHCID 170903Pentanal, 5,5-dimethoxy-

Product 1

HCID 58434562HCID 58434562, compoundYield 55.1%

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

Prepared according to the general procedure A from 1-nitropropane 112c (80 mmol) and 5,5-dimethoxypentanal 131 (16 mmol) to provide the title compound as yellow oil (1.51 g, 55% yield) after silica gel chromatography (EtOAc/Hexane).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-3e68881140b244c592c28c2896235107
Source dataset
uspto-grants-2014_03
Patent number
US08680335B2

Reaction notes

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