Phenethyl bromide → Ethanol, 2,2'-[(2-phenylethyl)imino]bis-

Reaction equation

[NH:1]([CH2:5][CH2:6][OH:7])[CH2:2][CH2:3][OH:4].Br[CH2:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[OH:4][CH2:3][CH2:2][N:1]([CH2:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[CH2:5][CH2:6][OH:7]

Participants

Reactant 2

HCID 7666Phenethyl bromide

HCID 8113Diethanolamine

Product 1

HCID 10987515Ethanol, 2,2'-[(2-phenylethyl)imino]bis-

Procedure

2-[(2-Hydroxy-ethyl)-(2-phenyl-ethyl)-amino]-ethanol was prepared according to the general method as outlined in example 1. Starting from diethanolamine (6.0 g, 57). and 2-bromo-ethylbenzene (9.0 g, 48.3 mmol). Yield 9 g, (90%); yellow oil; MS: 210 (M+H)+.

Sources & evidence

ORD record: ord-603c5351e5374a598f78995725069149
Source dataset: uspto-grants-2002_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06342508B1

Reaction notes

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