Benzoyl Peroxide → Ioa iba

HRID 1279668

Reaction equation

HRID 1279668 reaction equation
[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH3:14][C@@:15]12[CH:23]([C:24]([C:26]([O-:28])=[O:27])=[CH2:25])[CH2:22][C@H:18]([C:19]1([CH3:21])[CH3:20])[CH2:17][CH2:16]2.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.C(Br)(Br)(Br)Br>C(OCC)(=O)C>[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH3:14][C@@:15]12[CH:23]([C:24]([C:26]([O-:28])=[O:27])=[CH2:25])[CH2:22][C@H:18]([C:19]1([CH3:20])[CH3:21])[CH2:17][CH2:16]2

Participants

6

Reactant 4

HCID 7187Benzoyl PeroxideHCID 11205Carbon tetrabromideHCID 165746Isooctyl acrylateHCID 92004758Isobomyl acrylate

Product 1

HCID 131723481Ioa iba

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Conditions

Temperature
60 °C

Procedure

In a glass polymerization bottle were charged 80 g isooctyl acrylate (IOA), 18 g isobornyl acrylate (IBA), 2 g vinyldimethylazlactone (VDM), 100 g ethyl acetate, 0.5 g benzoyl peroxide and 0.04 g carbon tetrabromide. The bottle was purged with nitrogen, sealed and tumbled in a water bath maintained at 60° C. for 12 hours to produce a IOA/IBA/VDM terpolymer. The polymer was isolated by precipitation in isopropanol and dried under vacuum.

Workup

  1. customIn a glass polymerization bottle
  2. customThe bottle was purged with nitrogen
  3. customsealed
  4. customtumbled in a water bath

Sources & evidence

ORD record
ord-0f178365228a4680a63c0489ca01ac42
Source dataset
uspto-grants-2002_09
Patent number
US06448337B1

Linked notes

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