Hydrochloric Acid → Molybdenum 2,2,4-trimethyl decahydroquinoline

HRID 128365

Reaction equation

HRID 128365 reaction equation
[CH3:1][C:2]1([CH3:13])[CH2:11][CH:10]([CH3:12])[CH:9]2[CH:4]([CH2:5][CH2:6][CH2:7][CH2:8]2)[NH:3]1.Cl.[NH4+].[O-][Mo:17]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O>O>[Mo:17].[CH3:1][C:2]1([CH3:13])[CH2:11][CH:10]([CH3:12])[CH:9]2[CH:4]([CH2:5][CH2:6][CH2:7][CH2:8]2)[NH:3]1

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 21895884Azanium bis(dioxido(dioxo)molybdenum)HCID 226287862,2,4-Trimethyldecahydroquinoline

Product 1

HCID 131710931Molybdenum 2,2,4-trimethyl decahydroquinoline

Reagents, catalysts & solvents 1

HCID 962WaterSolvent3×

Procedure

2,2,4-Trimethyl decahydroquinoline molybdate having a 2/1 molybdenum/2,2,4-trimethyl decahydroquinoline molar ratio was prepared as follows. 10 grams 2,2,4-trimethyl decahydroquinoline, 16.30 grams of a 37 wt.% aqueous HCl solution and 250 ml water were dissolved together and heated to reflux in a 500 ml round-bottomed flask equipped with a stirrer and water-cooled condenser. 28.12 grams ammonium dimolybdate was dissolved in 50 ml hot water. The second solution was added to the first solution. A yellow precipitate formed immediately.

Workup

  1. temperatureheated
  2. temperatureto reflux in a 500 ml round-bottomed flask
  3. customequipped with a stirrer
  4. additionThe second solution was added to the first solution
  5. customA yellow precipitate formed immediately

Sources & evidence

ORD record
ord-60ebefb24ff74d1690c3e9d29862484a
Source dataset
uspto-grants-1981_03
Patent number
US04259491

Linked notes

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