2,3-Dichloro-5,6-dicyano-1,4-benzoquinone → HCID 66968737, compound
Reaction equation
C([O:6][C:7]1[C:13]([Cl:14])=[C:12]([Cl:15])[C:10]([OH:11])=[C:9]([Cl:16])[C:8]=1[Cl:17])CCCC.Cl[C:19]1[C:20](=O)[C:21](C#N)=C(C#N)[C:23](=O)[C:24]=1Cl>CO>[CH2:23]([C:13]1([Cl:14])[CH:12]([Cl:15])[C:10](=[O:11])[C:9]([Cl:16])=[C:8]([Cl:17])[C:7]1=[O:6])[CH2:24][CH2:19][CH2:20][CH3:21]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
To a solution of 110 mg (0.388 mmol) of 3 in methanol, 880 mg (10 eq) of 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) was added. The reaction mixture was stirred for 2 hr, and then the solvent was removed. Silicagel chromatography (hexane: EA=20:1) gave 4 as an orange solid with quantitative yield.
Workup
- customthe solvent was removed
Sources & evidence
- ORD record
- ord-e2f4913dea454fce8fa67bf0f1b39aa5
- Source dataset
- uspto-grants-2011_02
- Patent number
- US07888055B2
Reaction notes
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