m-Chloroperbenzoic acid → 86088-36-0
Reaction equation
[C:1]1([CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.ClC1C=CC=C(C(OO)=[O:20])C=1>ClCCl>[C:1]1([CH2:7][CH2:8][CH2:9][CH:10]2[CH2:11][O:20]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
5-Phenylpent-1-ene (14.2 g, 0.0973 mol) and m-chloroperbenzoic acid (16.79 g, 0.0973 mol) in dichloromethane (300 ml) was stirred at room temperature for 4 hours. The solution was washed with saturated aqueous sodium hydrogen carbonate solution and dried (MgSO4). The solvent was evaporated off under reduced pressure to give an oil which was distilled to give 2-(3-phenylpropyl)oxirane (b.p. 85° C., 0.4 mm.Hg).
Workup
- washThe solution was washed with saturated aqueous sodium hydrogen carbonate solution
- dry with materialdried (MgSO4)
- customThe solvent was evaporated off under reduced pressure
- customto give an oil which
- distillationwas distilled
Sources & evidence
- ORD record
- ord-205a8488e9cc4405b1ddfb57e7330eaa
- Source dataset
- uspto-grants-1986_04
- Patent number
- US04579862
Reaction notes
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