Dithiodibenzoic acid → 2,2'-Dithiobis[n-(tricyclo[3.3.1.13,7]dec-1-ylmethyl)-benzamide]

HRID 1384331

Reaction equation

HRID 1384331 reaction equation
[C:1]12([CH2:11][NH2:12])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[CH:13]1[CH:18]=[C:17]([C:19]([OH:21])=O)[C:16]([S:22][S:23][C:24]2[C:29]([C:30]([OH:32])=O)=[CH:28][CH:27]=[CH:26][CH:25]=2)=[CH:15][CH:14]=1>CN(C)C1C=CN=CC=1>[C:1]12([CH2:11][NH:12][C:30](=[O:32])[C:29]3[CH:28]=[CH:27][CH:26]=[CH:25][C:24]=3[S:23][S:22][C:16]3[CH:15]=[CH:14][CH:13]=[CH:18][C:17]=3[C:19]([NH:12][CH2:11][C:1]34[CH2:10][CH:5]5[CH2:4][CH:3]([CH2:9][CH:7]([CH2:6]5)[CH2:8]3)[CH2:2]4)=[O:21])[CH2:8][CH:7]3[CH2:6][CH:5]([CH2:4][CH:3]([CH2:9]3)[CH2:2]1)[CH2:10]2

Participants

4

Reactant 2

HCID 8409Dithiodibenzoic acidHCID 86625Tricyclo(3.3.1.13,7)dec-1-ylmethylamine

Product 1

HCID 881635242,2'-Dithiobis[n-(tricyclo[3.3.1.13,7]dec-1-ylmethyl)-benzamide]Yield 30.6%

Reagents, catalysts & solvents 1

HCID 142844-(Dimethylamino)pyridineCatalyst

Procedure

Prepared according to the method of Example 14 from 1-adamantanemethylamine (0.23 g), 4-dimethylaminopyridine (0.006 g) and 2,2′dithiosalicylic acid (0.2 g) to give the sub-title compound as an off-white solid (0.12 g).

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-d2fd3b4931a34f3a890ac3cd8b1f85fc
Source dataset
uspto-grants-2001_07
Patent number
US06258838B1

Linked notes

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