Ferrocenecarboxylic acid → Bis(eta-cyclopentadienyl) iron
Reaction equation
[C-:1]1(C(O)=O)[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14]>CCC(C)=O>[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:9]1[CH:13]=[CH:12][CH:11]=[CH:10]1.[Fe+2:14]Participants
3
Reactant 1
Product 1
Reagents, catalysts & solvents 1
Procedure
Coating solutions were prepared by refluxing ferrocene carboxylic acid and Zr n-propoxide, at 1:1 and 1:2 molar ratios of Zr:Fc, in MEK. Films were then spin coated on TEC 15 and cured at 125° C. for 8 hours. The resulting coatings, up to 1 μm thick, were hard and stable in the electrolyte and colored at 1.3 V.
Workup
- customCoating solutions were prepared
Sources & evidence
- ORD record
- ord-f12aa174c81d417b93623ce94a24fa90
- Source dataset
- uspto-grants-2001_07
- Patent number
- US06266177B1
Reaction notes
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