Trimethylsilyl cyanide → HCID 21862809, compound

Reaction equation

[CH3:1][C:2]1[CH:19]=[CH:18][C:5]([CH:6]=[N:7][C:8]2[CH:13]=[CH:12][C:11]([S:14](=[O:17])(=[O:16])[NH2:15])=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.C[Si]([C:24]#[N:25])(C)C>>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([CH:6]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([S:14](=[O:16])(=[O:17])[NH2:15])=[CH:10][CH:9]=2)[C:24]#[N:25])=[CH:18][CH:19]=1

Participants

Reactant 2

HCID 82115Trimethylsilyl cyanide

HCID 690836HCID 690836, compound

Product 1

HCID 21862809HCID 21862809, compound

Procedure

Following a procedure similar to that described in Example 1(ii), but using N-(4-methylbenzylidene)-4-sulfamoylaniline [prepared as described in step (i) above] and trimethylsilyl cyanide as starting materials, the title compound was obtained as a white powder (yield 94%).

Sources & evidence

ORD record: ord-cd7e54d5022b464e9e7b62f6c6f1aacf
Source dataset: uspto-grants-1999_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05908858

Reaction notes

Loading…