Iodonium, diphenyl-, bromide (1:1) → Phenyl benzoate

HRID 1447206Notes

Reaction equation

HRID 1447206 reaction equation
[Br-].[C:2]1([I+:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:15]([O-:23])(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[Na+]>>[C:15]([O:23][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)(=[O:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[C:2]1([I:8])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 73871Iodonium, diphenyl-, bromide (1:1)HCID 517055Sodium Benzoate

Product 2

HCID 7169Phenyl benzoateHCID 11575Iodobenzene

Procedure

Diphenyliodonium bromide has been reacted with sodium benzoate to form phenyl benzoate and phenyl iodide, and the reaction has been found to be faster in strong bases. F. M. Beringer, et al., 75 J. Amer. Chem. Soc. 2708 (1963).

Sources & evidence

ORD record
ord-8cce7a82156f4b91b7b2eaa733fc1ca6
Source dataset
uspto-grants-1982_02
Patent number
US04316046

Reaction notes

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