Hexane → 13-Phenyltridecanol

Reaction equation

C([O:4][CH2:5][CH3:6])(=O)C.[CH3:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]>>[C:9]1([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:6][CH2:5][OH:4])[CH:8]=[CH:7][CH:12]=[CH:11][CH:10]=1

Participants

Reactant 2

HCID 8058Hexane

HCID 8857Ethyl Acetate

Product 1

HCID 2184931413-Phenyltridecanol

Procedure

melting point=34°-36° C. Rf value: 0.24 (ethyl acetate:hexane=1:5); 1H-NMR (CDCl3 /TMS) δ: 1.28 & 1.57 (23H, 2br.s), 2.62 (2H, t, J=7.5 Hz), 3.65 (2H, t, J=6 Hz), 7.23 (5H, m); IR(KBr): 3344, 3259, 2918, 2848, 1468 cm-1 ; MS(EI): 276 (M+).

Sources & evidence

ORD record: ord-4dbc9b372c41443c8fb26231df3e0d8d
Source dataset: uspto-grants-1997_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05604229

Reaction notes

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