Reaction equation
[CH3:1][NH:2][CH3:3].[C:4](=[S:6])=[S:5].O=O>C(O)(C)C>[CH3:1][N:2]([C:4]([S:6][S:6][C:4]([N:2]([CH3:3])[CH3:1])=[S:5])=[S:5])[CH3:3]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 50 °C
Procedure
13.5 g (0.3 mol) of dimethylamine and 24.4 mg (0.1×10-3 mol) of Mn(CH3COO)2.4H2O were dissolved in 100 g of isopropanol in the reaction equipment described in Example 1. 22.8 g (0.3 mol) of carbon disulfide were added to this solution. The resulting clear, dark brown solution was heated to 50° C., stirred vigorously, and subjected to 1.7 bar of oxygen. Under these conditions, the reaction came to an end after 90 minutes. TMTD was obtained with a yield of 98.6%.
Sources & evidence
- ORD record
- ord-4a7a25c6d1f64aa2af5c0362cf7b9df1
- Source dataset
- uspto-grants-1984_07
- Patent number
- US04459424
Linked notes
Loading…