Dimethyl Sulfoxide → 4-Difluoromethoxy-3-(4-nitro-2-bromophenoxy)benzaldehyde

HRID 148081

Reaction equation

HRID 148081 reaction equation
[Br:16][c:17]1[c:18]([F:26])[cH:19][cH:20][c:21]([N+:23](=[O:24])[O-:25])[cH:22]1.[CH3:27][S:28]([CH3:29])=[O:30].[CH3:31][CH2:32][O:33][C:34](=[O:35])[CH3:36].[F-:14].[F:1][CH:2]([O:3][c:4]1[c:5]([OH:12])[cH:6][c:7]([CH:8]=[O:9])[cH:10][cH:11]1)[F:13].[K+:15]>>[F:1][CH:2]([O:3][c:4]1[c:5]([O:12][c:18]2[c:17]([Br:16])[cH:22][c:21]([N+:23](=[O:24])[O-:25])[cH:20][cH:19]2)[cH:6][c:7]([CH:8]=[O:9])[cH:10][cH:11]1)[F:13]

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 813Potassium CationHCID 8857Ethyl AcetateHCID 28179Fluoride IonHCID 696992-Bromo-1-fluoro-4-nitrobenzeneHCID 27582954-(Difluoromethoxy)-3-hydroxybenzaldehyde

Product 1

HCID 247582824-Difluoromethoxy-3-(4-nitro-2-bromophenoxy)benzaldehyde

Sources & evidence

ORD record
ord-d61858fe20cf47f0939dc8374082111d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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