Sodium ion → Di-tert-butyl (3-fluoro-4-nitrophenyl)malonate

HRID 150623

Reaction equation

HRID 150623 reaction equation
[C:12]([CH2:13][C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])(=[O:21])[O:22][C:23]([CH3:24])([CH3:25])[CH3:26].[CH2:29]1[O:30][CH2:31][CH2:32][CH2:33]1.[F:1][c:2]1[c:3]([N+:9](=[O:10])[O-:11])[cH:4][cH:5][c:6]([F:8])[cH:7]1.[H-:27].[Na+:28]>>[F:1][c:2]1[c:3]([N+:9](=[O:10])[O-:11])[cH:4][cH:5][c:6]([CH:13]([C:12](=[O:21])[O:22][C:23]([CH3:24])([CH3:25])[CH3:26])[C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])[cH:7]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 8028TetrahydrofuranHCID 679672,4-DifluoronitrobenzeneHCID 68324Di-tert-butyl malonateHCID 166653Hydride

Product 1

HCID 67407431Di-tert-butyl (3-fluoro-4-nitrophenyl)malonate

Sources & evidence

ORD record
ord-035b67996aaa4988a121c3b992d6b40f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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