HCID 178424007, compound → 7-Methylbenzo[d]thiazole
Reaction equation
[CH3:1][C:2]1[C:10]2[S:9][C:8](S)=[N:7][C:6]=2[CH:5]=[CH:4][CH:3]=1>C(O)(=O)C.[Fe]>[CH3:1][C:2]1[C:10]2[S:9][CH:8]=[N:7][C:6]=2[CH:5]=[CH:4][CH:3]=1Participants
4
Reactant 1
Product 1
Reagents, catalysts & solvents 2
Procedure
Following the same procedure as in step 2 of Example 337 using 7-methyl-1,3-benzothiazole-2-thiol (3.8 g, 20.96 mmol, 1.00 equiv) and iron powder (9.28 g, 171.85 mmol, 8.20 equiv) in acetic acid (24 mL) as a yellow oil.
Sources & evidence
- ORD record
- ord-44996eb4b7b4470eaa42aa80d52ddc8c
- Source dataset
- uspto-grants-2015_12
- Patent number
- US09221809B2
Reaction notes
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