3-Chloroaniline → Benzenamine, 3-chloro-, hydrochloride (1:1)

HRID 1602227

Reaction equation

HRID 1602227 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][CH:8]=1)[NH2:5]>Cl.CO>[ClH:1].[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][CH:8]=1)[NH2:5]

Participants

4

Reactant 1

HCID 79323-Chloroaniline

Product 1

HCID 67336Benzenamine, 3-chloro-, hydrochloride (1:1)

Reagents, catalysts & solvents 2

HCID 313Hydrochloric AcidSolventHCID 887MethanolSolvent

Procedure

60 g (0.47 mol) of 3-chloro-aniline are dissolved in 255 ml (0.56 mol) of a 2.2N solution of HCl in methanol. Concentration and stirring of the residue in diethyl ether, followed by filtering and drying, yield 3-chloro-aniline hydrochloride.

Workup

  1. concentrationConcentration
  2. filtrationby filtering
  3. customdrying

Sources & evidence

ORD record
ord-716cca8cf89f4b078fd6676e238ea6d7
Source dataset
uspto-grants-1999_11
Patent number
US05981533

Linked notes

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