N,N-Dimethyltetradecylamine → Phenoxycarbonylmethyltetradecyldimethyl ammonium bromide
Reaction equation
[Br:1][CH2:2][C:3]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:4].[CH2:12]([N:26]([CH3:28])[CH3:27])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[Br-:1].[O:5]([C:3]([CH2:2][N+:26]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])([CH3:27])[CH3:28])=[O:4])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1Participants
3
Procedure
A mixture of 55 g (0.26 mol) phenyl bromoacetate and 62 g (0.26 mol) of tetradecyldimethylamine was allowed to stand at room temperature for three days. The resultant crystalline mass was washed well with ether and dried to 114 g. Recrystallized from ethyl acetate and vacuum dried, the compound melted at 87°-91.5°.
Workup
- washThe resultant crystalline mass was washed well with ether
- customdried to 114 g
- customRecrystallized from ethyl acetate and vacuum
- customdried