Acetate → 4'-Chloro[1,1'-biphenyl]-4-carbaldehyde

HRID 160916

Reaction equation

HRID 160916 reaction equation
[Br:11][c:12]1[cH:13][cH:14][c:15]([CH:16]=[O:17])[cH:18][cH:19]1.[CH2:29]([CH2:30][O:31][CH3:32])[O:33][CH3:34].[Cl:1][c:2]1[cH:3][cH:4][c:5]([B:8]([OH:9])[OH:10])[cH:6][cH:7]1.[O-:21][C:22]([CH3:23])=[O:24].[O-:25][C:26]([CH3:27])=[O:28].[Pd+2:20]>>[Cl:1][c:2]1[cH:3][cH:4][c:5](-[c:12]2[cH:13][cH:14][c:15]([CH:16]=[O:17])[cH:18][cH:19]2)[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 175Acetate2×HCID 80711,2-DimethoxyethaneHCID 707414-BromobenzaldehydeHCID 742994-Chlorophenylboronic acidHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 5925704'-Chloro[1,1'-biphenyl]-4-carbaldehyde

Sources & evidence

ORD record
ord-c305e3d83929412493df88edf56681d3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Linked notes

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