Ammonium Hydroxide → 2,4-Dinitrobenzenesulfenamide

HRID 1633234Notes

Reaction equation

HRID 1633234 reaction equation
ClC1N=C(C=[N:11][S:12][C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[CH:15][C:14]=2[N+:22]([O-:24])=[O:23])C(N)=NC=1Cl.[N+](C1C=C([N+]([O-])=O)C=CC=1SCl)([O-])=O.[OH-].[NH4+]>>[N+:22]([C:14]1[CH:15]=[C:16]([N+:19]([O-:21])=[O:20])[CH:17]=[CH:18][C:13]=1[S:12][NH2:11])([O-:24])=[O:23]

Participants

4

Reactant 3

HCID 14923Ammonium HydroxideHCID 682512,4-Dinitrobenzenesulfenyl chlorideHCID 54475572HCID 54475572, compound

Product 1

HCID 1912072,4-Dinitrobenzenesulfenamide

Procedure

5,6-Dichloro-3-[(2,4-dinitrophenyl)thioimino]methylpyrazinamine by the reaction of 2,4-dinitrobenzenesulfenyl chloride with ammonium hydroxide to form 2,4-dinitrobenzenesulfenamide, followed by the reaction of the latter with 3-amino-5,6-dichloropyrazinaldehyde.

Sources & evidence

ORD record
ord-e4092bf556824af3b154cefd4c1d8c85
Source dataset
uspto-grants-1984_10
Patent number
US04479953

Reaction notes

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