Phenothiazine → 3-(Trichlorosilyl)propyl methacrylate

HRID 1686371Notes

Reaction equation

HRID 1686371 reaction equation
[C:1]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])[C:2]([CH3:4])=[CH2:3].[Cl:10][SiH:11]([Cl:13])[Cl:12].C1C2NC3C(=CC=CC=3)SC=2C=CC=1.CCCCCCCCCCCCCCCCCCOC(CCSCCC(OCCCCCCCCCCCCCCCCCC)=O)=O>>[C:1]([O:6][CH2:7][CH2:8][CH2:9][Si:11]([Cl:13])([Cl:12])[Cl:10])(=[O:5])[C:2]([CH3:4])=[CH2:3]

Participants

5

Reactant 4

HCID 7108PhenothiazineHCID 7274Allyl methacrylateHCID 12738Distearyl ThiodipropionateHCID 24811Trichlorosilane

Product 1

HCID 818113-(Trichlorosilyl)propyl methacrylate

Conditions

Temperature
150 °C

Procedure

A methacryloxypropyl trichlorosilane was synthesized by a known method where allyl methacrylate and trichlorosilane were used as starting materials. 20 g of the obtained product and 5 mg of a styrenated phenothiazine (ANTAGE STDP-N, molecular weight was 407.6; the product of Kawaguchi Chemical Company, Ltd.) was sealed in a bottle with a threaded cap and heated in a 150° C. oil bath. The obtained product was not gelled and maintained flowability even 20 hours after the above-described treatment.

Workup

  1. custom) was sealed in a bottle with
  2. customa threaded cap
  3. temperaturemaintained flowability even 20 hours after the above-described treatment

Sources & evidence

ORD record
ord-b66a1b0f1b0f49518ee074ea3026aa38
Source dataset
uspto-grants-2012_04
Patent number
US08148565B2

Reaction notes

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