1-Bromodecane → Decyl thiocyanate

HRID 1730382

Reaction equation

HRID 1730382 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[S-:12][C:13]#[N:14].[Na+].[Cl-].C(C([NH3+])(C(=O)CCCCCCC)C(=O)CCCCCCC)(=O)CCCCCCC>O>[S:12]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[C:13]#[N:14]

Participants

5

Reactant 3

HCID 81731-BromodecaneHCID 516871Sodium thiocyanateHCID 77620884Tricaprylylmethyl ammonium chloride

Product 1

HCID 79301Decyl thiocyanate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 100 grams (0.45 mole) of 1-bromodecane, 160 grams (1.98 moles)of sodium thiocyanate, 50 ml water and 10 grams of tricaprylylmethylammonium chloride was heated to 88°-105° C with stirring over a period of 2 hours. Examination of the reaction mixture by gas liquid partition chromatography showed that 100% conversionof the 1-bromodecane had occurred to give 1-thiocyanodecane.

Workup

  1. temperaturewas heated to 88°-105° C
  2. customExamination of the reaction mixture by gas liquid partition chromatography

Sources & evidence

ORD record
ord-40daf765ff7f42f69c9e152c4d0c32ab
Source dataset
uspto-grants-1976_11
Patent number
US03992432

Linked notes

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