Water → 4-(1,3-Dithian-2-ylidene)-6-fluoro-3,4-dihydro-2H-chromene

HRID 176863

Reaction equation

HRID 176863 reaction equation
[CH2:11]([Li:12])[CH2:13][CH2:14][CH3:15].[CH3:1][Si:2]([CH:3]1[S:4][CH2:5][CH2:6][CH2:7][S:8]1)([CH3:9])[CH3:10].[CH3:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].[F:16][c:17]1[cH:18][c:19]2[c:24]([cH:25][cH:26]1)[O:23][CH2:22][CH2:21][C:20]2=[O:27].[O:29]1[CH2:30][CH2:31][CH2:32][CH2:33]1.[OH2:28]>>[C:3]1(=[C:20]2[c:19]3[cH:18][c:17]([F:16])[cH:26][cH:25][c:24]3[O:23][CH2:22][CH2:21]2)[S:4][CH2:5][CH2:6][CH2:7][S:8]1

Participants

7

Reactant 6

HCID 962WaterHCID 8028TetrahydrofuranHCID 8058HexaneHCID 834132-Trimethylsilyl-1,3-dithianeHCID 27332626-fluoro-2,3-dihydro-4H-1-benzopyran-4-oneHCID 178418339Butyllithium

Product 1

HCID 544848744-(1,3-Dithian-2-ylidene)-6-fluoro-3,4-dihydro-2H-chromene

Sources & evidence

ORD record
ord-f84d777cd9d04cc79f672c69c436c8ec
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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