Potassium Cation → 6-Bromo-2a-[4-(2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-2-yl)-butyl]-2a,3,4,5-tetrahydro-1H-benz[cd]indol-2-one

HRID 179476

Reaction equation

HRID 179476 reaction equation
[Br:20][c:21]1[c:22]2[c:23]3[c:27]([cH:28][cH:29]1)[NH:26][C:25](=[O:30])[C:24]3([CH2:34][CH2:35][CH2:36][CH2:37][Br:38])[CH2:31][CH2:32][CH2:33]2.[C:14](=[O:15])([O-:16])[O-:17].[CH2:1]1[NH:2][CH2:3][CH2:4][c:5]2[c:6]1[nH:7][c:8]1[cH:9][cH:10][cH:11][cH:12][c:13]21.[K+:18].[K+:19].[O:39]=[CH:40][N:41]([CH3:42])[CH3:43]>>[CH2:1]1[N:2]([CH2:37][CH2:36][CH2:35][CH2:34][C:24]23[c:23]4[c:22]([c:21]([Br:20])[cH:29][cH:28][c:27]4[NH:26][C:25]2=[O:30])[CH2:33][CH2:32][CH2:31]3)[CH2:3][CH2:4][c:5]2[c:6]1[nH:7][c:8]1[cH:9][cH:10][cH:11][cH:12][c:13]21

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 107838Tetrahydro-beta-carbolineHCID 109819466-Bromo-2a-(4-bromobutyl)-2a,3,4,5-tetrahydrobenz[cd]indole-2(1H)-one

Product 1

HCID 183773546-Bromo-2a-[4-(2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-2-yl)-butyl]-2a,3,4,5-tetrahydro-1H-benz[cd]indol-2-one

Sources & evidence

ORD record
ord-4351916237bc4d11b8bbbd589ad86363
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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