2-(Methylamino)ethanol → C7F15C(O)N(CH3)C2H4OH

HRID 1828009

Reaction equation

HRID 1828009 reaction equation
[C:1]([C:23](OC)=[O:24])([C:4]([C:7]([C:10]([C:13]([C:16]([C:19]([F:22])([F:21])[F:20])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[CH3:27][NH:28][CH2:29][CH2:30][OH:31]>C1COCC1>[C:1]([C:23]([N:28]([CH2:29][CH2:30][OH:31])[CH3:27])=[O:24])([C:4]([C:7]([C:10]([C:13]([C:16]([C:19]([F:20])([F:22])[F:21])([F:18])[F:17])([F:15])[F:14])([F:11])[F:12])([F:8])[F:9])([F:6])[F:5])([F:2])[F:3]

Participants

4

Reactant 2

HCID 80162-(Methylamino)ethanolHCID 67824Methyl perfluorooctanoate

Product 1

HCID 102189403C7F15C(O)N(CH3)C2H4OHYield 76.4%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

C7F15C(O)N(CH3)C2H4OH was prepared by combining n-C7F15CO2CH3 (85 grams) and CH3NHCH2CH2OH (16.5 grams) in THF (50 grams) at 50° C. Progress of the reaction was monitered by GC and FTIR spectra. The isolated yield was 76.4% of C7F15C(O)N(CH3)C2H4OH. (b.p.: 110–125° C./1.5–3 mmHg).

Workup

  1. customC7F15C(O)N(CH3)C2H4OH was prepared
  2. customat 50° C

Sources & evidence

ORD record
ord-1e74967e85b7416aadd933730eb5dc30
Source dataset
uspto-grants-2006_06
Patent number
US07056846B2

Linked notes

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