HCID 11439448, compound → HCID 9968509, compound
Reaction equation
[C:1]([O:5][C:6]([NH:8][C@@H:9]([CH3:25])[C:10]([N:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH2:14][C@H:13]1[C:21]([O:23][CH3:24])=[O:22])=[O:11])=[O:7])([CH3:4])([CH3:3])[CH3:2]>CO.[Rh]>[C:1]([O:5][C:6]([NH:8][C@@H:9]([CH3:25])[C:10]([N:12]1[C@@H:20]2[C@@H:15]([CH2:16][CH2:17][CH2:18][CH2:19]2)[CH2:14][C@H:13]1[C:21]([O:23][CH3:24])=[O:22])=[O:11])=[O:7])([CH3:4])([CH3:3])[CH3:2]Participants
4
Reactant 1
Product 1
Reagents, catalysts & solvents 2
Procedure
The residue obtained in Example 1 (1 kg) is dissolved in methanol and transferred to a hydrogenator, and then 0.10 kg of 5% rhodium-on-carbon is added.
Sources & evidence
- ORD record
- ord-5a902643ab434bd19f494fb095ee854a
- Source dataset
- uspto-grants-2006_06