m-Chloroperbenzoic acid → HCID 20392342, compound

HRID 1863211Notes

Reaction equation

HRID 1863211 reaction equation
[CH3:1][C:2]1[CH:11]=[C:10]([O:12][C:13]([N:15]([CH3:17])[CH3:16])=[O:14])[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.ClC1C=CC=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:11]=[C:10]([O:12][C:13]([N:15]([CH3:16])[CH3:17])=[O:14])[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N+:3]=1[O-:26]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 127982362-Methyl-4-dimethylaminocarbonyloxyquinoline

Product 1

HCID 20392342HCID 20392342, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

23 g (0.1 mole) of 2-methyl-4-dimethylaminocarbonyloxyquinoline were dissolved in 150 ml of dry chloroform free of alcohol and, while stirring and externally cooling with ice-water, 25 g 3-chloroperbenzoic acid (70% strength) dissolved in 400 ml chloroform were added dropwise.

Workup

  1. additionwere added dropwise

Sources & evidence

ORD record
ord-4457167b4c17466e9693ecceedb0c43a
Source dataset
uspto-grants-1979_09
Patent number
US04168311

Reaction notes

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