Water → HCID 57448062, compound
Reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8][CH3:9])[C:3]=1[CH3:10].C(Cl)(Cl)(Cl)Cl.C(#N)C.I([O-])(=O)(=O)=[O:20].[Na+].[OH2:25]>[Ru](Cl)(Cl)Cl>[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8]([CH3:9])(=[O:20])=[O:25])[C:3]=1[CH3:10]Participants
7
Reactant 5
Product 1
Reagents, catalysts & solvents 1
Procedure
Preparation according to preparation 4: 1-bromo-2-methyl-3-(methylthio)benzene (1.33 g), carbon tetrachloride (8 ml), acetonitrile (8 ml), water (16 ml), sodium periodate (3.9 g), ruthenium trichloride (1 mg). Yield: 1.6 g. MS m/z (rel. intensity, 70 eV) 250 (M+, 69), 248 (M+, 67), 169 (49), 90 (63), 89 (bp).
Workup
- customPreparation
- customaccording to preparation 4
Sources & evidence
- ORD record
- ord-d615e548032c4946ac30b0abc244da97
- Source dataset
- uspto-grants-2012_11
- Patent number
- US08314126B2
Reaction notes
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