HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butyl hydroperoxide → Tris-(4-benzoyloxy-2,2,6,6-tetramethyl-piperidin-1-yloxy)octadecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Reactant | Octadecane | HCID 11635 | — |
| Reactant | 1-Hydroxy-4-benzoyloxy-2,2,6,6-tetramethylpiperidine | HCID 688178 | — |
| Catalyst | Molybdenum trioxide | HCID 14802 | — |
| Product | Tris-(4-benzoyloxy-2,2,6,6-tetramethyl-piperidin-1-yloxy)octadecane | HCID 23372129 | — |
Reaction Steps
A mixture of 80 mmol of 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine, 250 mmol of 90% tert-butyl hydroperoxide, 125 grams of octadecane and 5 mmol of molybdenum trioxide is heated ait 140° C. in a Fischer-Porter prerssure bottle till the red color of the N-oxyl compound is no longer visible. The reaction mixture is purified by flash chromatography.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05574162 |
| Source dataset | uspto-grants-1996_11 |
| ORD ID | ord-e5bd1ca60c204db99c67898a5739116e |
| Source note | uspto-grants-1996_11 |