HRID1900303

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6410

tert-Butyl hydroperoxide

C4H10O2

HCID11635

Octadecane

C18H38

HCID688178

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCCCCC(ON1C(C)(C)CC(OC(=O)c2ccccc2)CC1(C)C)(ON1C(C)(C)CC(OC(=O)c2ccccc2)CC1(C)C)ON1C(C)(C)CC(OC(=O)c2ccccc2)CC1(C)C

HCID23372129

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID14802

Molybdenum trioxide

MoO3

PROCEDURE

实验过程

A mixture of 80 mmol of 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine, 250 mmol of 90% tert-butyl hydroperoxide, 125 grams of octadecane and 5 mmol of molybdenum trioxide is heated ait 140° C. in a Fischer-Porter prerssure bottle till the red color of the N-oxyl compound is no longer visible. The reaction mixture is purified by flash chromatography.

WORKUP

后处理

customThe reaction mixture is purified by flash chromatography

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e5bd1ca60c204db99c67898a5739116e
来源数据集: uspto-grants-1996_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05574162
来源说明: uspto-grants-1996_11

反应 SMILES

[C:1]([O:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[N:13]([OH:18])[C:12]([CH3:20])([CH3:19])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:21]([O:25]O)([CH3:24])([CH3:23])C.[CH3:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]>[Mo](=O)(=O)=O>[C:1]([O:9][CH:10]1[CH2:11][C:12]([CH3:20])([CH3:19])[N:13]([O:18][C:44]([O:18][N:13]2[C:12]([CH3:20])([CH3:19])[CH2:11][CH:10]([O:9][C:1](=[O:8])[C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH2:15][C:14]2([CH3:16])[CH3:17])([O:18][N:13]2[C:14]([CH3:16])([CH3:15])[CH2:24][CH:21]([O:25][C:1](=[O:8])[C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)[CH2:23][C:12]2([CH3:19])[CH3:11])[CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH3:27])[C:14]([CH3:16])([CH3:17])[CH2:15]1)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1